In the present work, the photocatalytic efficiency of a novel system based on ZnO doped with nitrogen (ZT) and supported on graphene oxide (GO) is investigated. ZnO synthesis and their N doping were carried out in a microwave reactor using thiourea as nitrogen source, while the GO was prepared through a variation of the Hummers' method. Structural, morphological and photochemical characterization of the developed material was performed by X-ray diffraction (XRD), UV-Vis spectroscopy, energy dispersive spectroscopy (EDS), scanning electron microscopy (SEM), analysis by X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy. The compounds were used to photodegrade the methylene blue molecule, which confirms the efficiency of nitrogen doped supported system compared to pristine ZnO. The degradation percentage of MB under UV energy using nitrogen-doped ZnO/GO, in a time of 35 min, reached 98% degradation; while using visible light 93% of degradation was reached.
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http://dx.doi.org/10.1016/j.chemosphere.2019.124368 | DOI Listing |
J Environ Manage
January 2025
Interdisciplinary Research Center for Construction and Building Materials, Department of Materials Science and Engineering, King Fahd University of Petroleum & Minerals, Dhahran, 31261, Saudi Arabia. Electronic address:
Mercury (Hg) pollution poses a critical threat to human health and the environment, necessitating urgent control measures. This study introduces a novel modification method for the common zero-valent iron-carbon (ZVI-AC) galvanic cells using a two-step process, nonthermal (NTP) irradiation followed by targeted functionalization, aiming to enhance Hg adsorption potential by adjusting the physicochemical properties of the cells. The NTP irradiated functionalized adsorbent demonstrated superior Hg adsorption performance across various concentrations and pH variations.
View Article and Find Full Text PDFFood Chem
January 2025
Materials Research Institute and Department of Ecosystem Science and Management, 204 Energy and the Environment Laboratory, The Pennsylvania State University, University Park, PA 16802, USA. Electronic address:
This work presents a convenient and easy-to-operate method for synthesizing the functionally integrated nanocomposite of nitrogen-doped multi walled carbon nanotube networks (N-CNTs) and cobalt 2-methylimidazole (ZIF-67) nanoparticles. The N-CNTs@ZIF-67 nanocomposite was utilized to design a novel electrochemical sensing platform for detecting gallic acid (GA). The N-CNTs@ZIF-67 modified glass carbon electrode (GCE) demonstrated high sensitivity for GA electrochemical detection (LOD: 10.
View Article and Find Full Text PDFNanotechnology
January 2025
Qingdao University, Ningxia Road 308, Qingdao, Shandong, 266071, CHINA.
Graphitic carbon nitride (g-C3N4) has gained significant attention as a promising nonmetallic semiconductor photocatalyst due to its photochemical stability, favorable electronic properties, and efficient light absorption. Nevertheless, its practical applications are hindered by limitations such as low specific surface area, rapid recombination of photogenerated charge carriers, poor electrical conductivity, and restricted photo-response ranges. This review explores recent advancements in the synthesis, modification and application of g-C3N4 and its nanocomposites with a focus on addressing these challenges.
View Article and Find Full Text PDFAdv Mater
January 2025
School of Chemistry and Chemical Engineering, Testing Center, Yangzhou University, Yangzhou, 225009, P. R. China.
As an alternative to bulk counterparts, metal-organic framework (MOF) nanoparticles isolated within conductive mesoporous carbon matrices are of increasing interest for electrochemical applications. Although promising, a "clean" carbon surface is generally associated with poor compatibility and weak interactions with metal/ligand precursors, which leads to the growth of MOFs with inhomogeneous particle sizes on outer pore walls. Here, a general methodology for in situ synthesis of eight nanoMOF composites within mesochannels with high dispersity and stability are reported.
View Article and Find Full Text PDFChem Sci
January 2025
Interdisciplinary Research Center for Sustainable Energy Science and Engineering (IRC4SE2), School of Chemical Engineering, Zhengzhou University Henan 450001 China
The exceptional oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) performances of core-shell catalysts are well documented, yet their activity and durability origins have been interpreted only based on the static structures. Herein we employ a NiFe alloy coated with a nitrogen-doped graphene-based carbon shell (NiFe@NC) as a model system to elucidate the active structure and stability mechanism for the ORR and OER by combining constant potential computations, molecular dynamic simulations, and experiments. The results reveal that the synergistic effects between the alloy core and carbon shell facilitate the formation of Fe-N-C active sites and replenish metal sites when central metal atoms detach.
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