Creasing instability is ubiquitous in soft solids; however, its inception remains enigmatic as it cannot be captured by the standard linearization techniques. It also does not fit the conventional picture of a barrier-crossing nucleation, and instead carries some features of a second order phase transition. Here we show that despite its fundamentally nonlinear nature, creasing has its origin in marginal stability which is, however, obscured by the dominance of long-range elastic interactions. We argue that despite its supercritical (soft) character, creasing bifurcation can be identified by the condition that the (generalized) driving force acting on an incipient stress singularity degenerates. The analytic instability criterion, obtained in this way, shows an excellent agreement with both physical experiments and direct numerical simulations.
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http://dx.doi.org/10.1103/PhysRevLett.122.248001 | DOI Listing |
Angew Chem Int Ed Engl
January 2025
Material Science Division, Argonne National Laboratory, 9700 South Cass Avenue, Lemont, Illinois, 60439, United States.
Exposure of soft material templates to alternating volatile chemical precursors can produce inorganic deposition within the permeable template (e.g. a polymer thin film) in a process akin to atomic layer deposition (ALD).
View Article and Find Full Text PDFAdv Mater
January 2025
Hefei National Research Center for Physical Sciences at the Microscale, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, 230026, P. R. China.
Calcium metal batteries with high capacity and low cost are promising alternatives to Li-ion batteries for large-scale energy storage. However, its development is crucially impeded by the irreversible Ca metal anode, which is highly associated with uncontrollable Ca plating/stripping. Here, we report a new riveting strategy to regulate the nucleation and growth of a Ca metal anode in the 3D structure of a carbon nanotube film (CNF) by introducing in situ-formed Na metal mediators.
View Article and Find Full Text PDFJ Chem Phys
January 2025
Soft Condensed Matter & Biophysics, Debye Institute for Nanomaterials Science, Utrecht University, Princetonplein 1, 3584 CC Utrecht, The Netherlands.
Since the influential work of ten Wolde, Ruiz-Montero, and Frenkel [Phys. Rev. Lett.
View Article and Find Full Text PDFAcc Chem Res
January 2025
Department of Chemistry, McGill University, 801 Sherbrooke Street West, Montreal, Quebec H3A 0B8, Canada.
ConspectusStructural DNA nanotechnology offers a unique self-assembly toolbox to construct soft materials of arbitrary complexity, through bottom-up approaches including DNA origami, brick, wireframe, and tile-based assemblies. This toolbox can be expanded by incorporating interactions orthogonal to DNA base-pairing such as metal coordination, small molecule hydrogen bonding, π-stacking, fluorophilic interactions, or the hydrophobic effect. These interactions allow for hierarchical and long-range organization in DNA supramolecular assemblies through a DNA-minimal approach: the use of fewer unique DNA sequences to make complex structures.
View Article and Find Full Text PDFJ Chem Phys
January 2025
Department of Chemistry, Indian Institute of Science Education and Research (IISER) Tirupati, Tirupati, Andhra Pradesh 517619, India.
Although impurities are unavoidable in real-world and experimental systems, most numerical studies on nucleation focus on pure (impurity-free) systems. As a result, the role of impurities in phase transitions remains poorly understood, especially for systems with complex free energy landscapes featuring one or more intermediate metastable phases. In this study, we employed Monte Carlo simulations to investigate the effects of static impurities (quenched disorder) of varying length scales and surface morphologies on the crystal nucleation mechanism and kinetics in the Gaussian core model system-a representative model for soft colloidal systems.
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