Salt-based preservation is practiced for decades in the leather industry because of its versatility, cost-effectiveness, and availability. The salt removed from the soaking process causes significant pollution including organic and elevated total dissolved solids (TDS). Hence, a low-salt skin preservation method using commercial sodium polyacrylate with a reduced quantity of sodium chloride aiming to retain leather properties and pollution reduction was the principal focus of the study. Commercial sodium polyacrylate initially characterized for water absorption capacity along with structural and functional properties is confirmed by NMR and IR spectroscopic techniques. In preliminary experiments, the process parameters attained optimized conditions of sodium polyacrylate (SPA) quantity (5%), a minimal amount of salt (15%), and contact time (4 h) required for skin preservation. Besides, reusability studies after SPA recovery (95%) were applied to skins with an optimized quantity of SPA and salt subsequently stored for 15 days along with control (40% salt). The results revealed that SPA with low salt aided an adequate curing efficiency with a substantial reduction (> 65%) of TDS and comparable physical and organoleptic properties on par with the conventional method. Overall, SPA supported low-salt skin preservation reduces pollutant load (TDS) caused due to using of 40% sodium chloride in the conventional curing process.
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http://dx.doi.org/10.1007/s11356-019-05871-y | DOI Listing |
Heliyon
January 2025
Department of Pharmaceutical Science, Faculty of Pharmacy, Umm Al-Qura University, Makkah, P.O. Box 751, Saudi Arabia.
This study presents the synthesis and application of water-ball (sodium polyacrylate) stabilized zero-valent iron nanoparticles (wb@Fe) for the eco-friendly degradation of Methyl Orange (MO). The nanoparticles were prepared using a chemical reduction method using NaBH. Characterization techniques including Field Emission Scanning Electron Microscopy (FESEM), Energy Dispersive X-ray Spectroscopy (EDS), Fourier Transform Infrared Spectroscopy (FTIR), X-ray Photoelectron Spectroscopy (XPS), and X-ray Diffraction (XRD) were employed to analyze the morphology, elemental composition, valent state and crystallinity of the nanoparticles.
View Article and Find Full Text PDFSmall
January 2025
School of Mechanical Engineering, Guangxi University, Nanning, 530004, P. R. China.
Flexible zinc-air batteries (FZABs) present a promising solution for the next generation of power sources in wearable electronics, owing to their high energy density, cost-effectiveness, and safety. However, solid-state electrolytes for FZABs continue to face challenges related to rapid water loss and low ionic conductivity. In this study, a hydrophilic and stable tetramethylguanidine-modified graphene oxide as an additive, which is incorporated into sodium polyacrylate to develop a high-performance gel polymer electrolyte (GPE), is designed.
View Article and Find Full Text PDFCarbohydr Polym
March 2025
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, 15 North Third Ring Road East, Chaoyang District, Beijing 100029, China. Electronic address:
Conductive hydrogels have emerged as excellent candidates for the design and construction of flexible wearable sensors and have attracted great attention in the field of wearable sensors. However, there are still serious challenges to integrating high stretchability, self-healing, self-adhesion, excellent sensing properties, and good biocompatibility into hydrogel wearable devices through easy and green strategies. In this paper, multifunctional conductive hydrogels (PCGB) with good biocompatibility, high tensile (1694 % strain), self-adhesive, and self-healing properties were fabricated by incorporating boric acid (BA) and glucose (Glu) simultaneously into polyacrylic acid (PAA) and chitosan (CS) polymer networks using a simple one-pot polymerization method.
View Article and Find Full Text PDFBMC Oral Health
January 2025
Faculty of Dentistry, Basic Medical Sciences Department, Ankara University, Ankara, 06560, Turkey.
Background: This study aimed to comparatively evaluate the effects of different cavity conditioners on internal adaptation (IA) of glass ionomer-based restorative materials applied to primary teeth.
Methods: 80 extracted primary second molar teeth were randomly assigned to four different cavity conditioner groups [10% polyacrylic acid, 20% polyacrylic acid, 17% ethylene diamine tetraacetic acid (EDTA), 35% phosphoric acid]. Class V cavities were prepared on the buccal surfaces and relevant cavity conditioners were applied, and the samples in each cavity conditioner group were randomly assigned to glass hybrid (GHR) or conventional glass ionomer restoratives (CGIR).
Biomolecules
December 2024
Institute of Fundamental Medicine and Biology, Kazan Federal University, 18 Kremlyovskaya St., 420008 Kazan, Russia.
The article is devoted to the creation of enzymatic nanoreactors based on polystyrene-block-poly(acrylic acid) (PS-b-PAA) copolymers containing bioscavengers capable of neutralizing toxic esters both in the body and in the environment. Block copolymers of different amphiphilicity, hydrophilicity and molecular weights were synthesized and characterized using gel permeation chromatography, NMR and UV spectroscopy. Polymeric nanocontainers in the absence and presence of human butyrylcholinesterase were made by film hydration and characterized by dynamic light scattering and microscopy methods.
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