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Stabilizing a High-Voltage Lithium-Rich Layered Oxide Cathode with a Novel Electrolyte Additive. | LitMetric

Stabilizing a High-Voltage Lithium-Rich Layered Oxide Cathode with a Novel Electrolyte Additive.

ACS Appl Mater Interfaces

Guangzhou Tinci Material Technology Co., Ltd , Guangzhou 510760 , China.

Published: August 2019

AI Article Synopsis

Article Abstract

We report a novel electrolyte additive, bis(trimethylsilyl)carbodiimide, that effectively stabilizes high-voltage lithium-rich oxide cathode. Charge/discharge tests demonstrate that even trace amounts of bis(trimethylsilyl)carbodiimide in a baseline electrolyte improve the cycling stability of this cathode significantly, either in Li-based half cells or graphite-based full cells, where the capacity retention after 200 cycles between 2 and 4.8 V at 0.5C is enhanced from 40 to 72% and 49 to 77%, respectively. Analyses using physical characterization and theoretical calculations reveal that this additive not only builds a protective film on the cathode but also eliminates detrimental hydrogen fluoride via its strong coordination with hydrogen fluoride or protons.

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Source
http://dx.doi.org/10.1021/acsami.9b07441DOI Listing

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