In this study, the impact of the curing temperature on leaching behaviour and durability of GGBS-MgO-CaO (GMC)-stabilized/GMC-solidified Pb/Zn-contaminated clay soils was investigated. Toxicity characteristic leaching procedure (TCLP) test, wetting-drying cycles, freeze-thaw cycles and unconfined compression strength (UCS) test were carried out. The influence of curing temperature, binder dosage and curing time on the performance of these samples was investigated. The results show that the leachability and the durability of all samples were improved by increasing curing temperature, curing time and binder dosage. GMCs are more functional in immobilizing Pb compared with Zn, especially in immobilizing high Pb-contaminated soils. The mass loss and Pb/Zn leachability of all samples increased, while their strength decreased after cyclic wetting-drying and cyclic freeze-thaw. Furthermore, curing at 21 °C and 45 °C, the freeze-thaw resistance of 10% GMC-treated soil (GMC10) was found better than that of 10% Portland cement-treated soil (PC10). After 10 cycles of wetting-drying, GMC10 is more chemically stable than PC10.
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http://dx.doi.org/10.1007/s11356-019-05894-5 | DOI Listing |
Mater Horiz
January 2025
State Key Laboratory of Organic-Inorganic Composites, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China.
Solar energy sources have garnered significant attention as a renewable energy option. Despite this, the practical power conversion efficiency (PCE) of widely used silicon-based solar cells remains low due to inefficient light utilization. In this study, carbon dots (APCDs) were prepared a hydrothermal method using ammonium polyphosphate and -phenylenediamine, then incorporated into a silicone-acrylic emulsion (CAS) to create a luminescent down-shifting (LDS) layer for solar cells.
View Article and Find Full Text PDFJ Chem Theory Comput
January 2025
Centre for Computational Science, University College London, 20 Gordon Street, London WC1H 0AJ, U.K.
For the computational design of new polymeric materials, accurate methods for determining the glass transition temperature () are required. We apply an ensemble approach in molecular dynamics (MD) and examine its predictions of and their associated uncertainty. We separate the uncertainty into the aleatoric contributions arising from dynamical chaos and that due to the computational scenarios chosen to compute .
View Article and Find Full Text PDFPolymers (Basel)
January 2025
LEPABE-Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, s/n, 4200-465 Porto, Portugal.
The food packaging industry is one of the fastest growing sectors of our economy, with a large contribution to environmental concerns due to the extensive use of fossil-derived materials. Combining wood-based materials, such as particleboards, with bio-adhesives may offer a great opportunity to develop sustainable packaging solutions with active antioxidant properties. In the present work, a phenolic extract of poplar bark was produced and bio-adhesives were formulated using citric acid as a cross-linker.
View Article and Find Full Text PDFPolymers (Basel)
January 2025
School of Civil Engineering and Transportation, Northeast Forestry University, Harbin 150040, China.
This article systematically investigated the improvement effect of polypropylene fiber (PPF) on the mechanical and freeze-thaw properties of alkali-activated fly ash slag concrete (AAFSC) with high fly ash content and cured at room temperature. Fly ash and slag were used as precursors, with fly ash accounting for 80% of the total mass. A mixed solution of sodium hydroxide and sodium silicate was used as alkali activator, and short-cut PPF was added to improve the performance of AAFSC.
View Article and Find Full Text PDFPolymers (Basel)
January 2025
College of Resources, Environment and Materials, Guangxi University, Nanning 530004, China.
In this paper, alumina-modified wood liquefaction (AL-WP) was prepared by blending nano-alumina (AlO) into wood liquefaction phenolic resin (WP) using a co-blending method. Alumina-modified wood liquefaction protofilament fiber (AL-WPF) was obtained by melt-spinning, curing, and thermo-curing processes, which were followed by carbonization to obtain alumina-modified wood liquefaction carbon fiber (AL-WCF). This paper focuses on the enhancement effect of nano-alumina doping on the mechanical properties and heat resistance of wood liquefaction carbon fiber (WCF), explores the evolution of graphite microcrystalline structure during the high-temperature carbonization process, and optimizes the curing conditions of AL-WPF.
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