We report an investigation on the synthesis, structure and magnetic properties of a series of heteroleptic Zn/Ln complexes of the general formula [ZnLClLn(o-van)(HO)(NO)]·HO (HL = N,N'-bis(3-methoxysalicylidene)-1,2-diaminoethane; o-van = o-vanillinate; Ln = Tb (1), Dy (2), Er (3)). All the compounds exhibit a slow relaxation of their magnetization and the dysprosium analogue shows one of the highest anisotropic barriers for ZnDy complexes.
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| http://dx.doi.org/10.1039/c9dt02228g | DOI Listing |
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