The increase in energy density of the next generation of battery materials to meet the new challenges of the electrical vehicles era calls for innovative and easily scalable materials with sustainable processes. An innovative Cu O/C nanocomposite material, characterized by a highly conductive 3D-framework, with Cu O/Cu-metal contiguous nanodomains is prepared by electrospinning. The electrode processing is made using a polyacrylic acid binder. The nanocomposite has been fully characterized and the electrochemical performance shows high specific capacity values over 450 galvanostatic cycles at 500 mAg specific current with capacity retention values over 80 %. In addition, the composite shows remarkable high rate performance and highly stable interface, which has been studied by impedance spectroscopy.
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http://dx.doi.org/10.1002/open.201900174 | DOI Listing |
Chemosphere
December 2024
Department of Chemical and Materials Engineering, National University of Kaohsiung, Kaohsiung 81148, Taiwan. Electronic address:
Visible light photocatalysts hold great promise for water purification, yet research on highly efficient, non-toxic photocatalysts is limited. This study synthesized novel g-CN/AlOOH photocatalytic nanocomposites via thermal condensation, enhancing adsorption and visible light degradation by 36-fold and 11-fold, respectively, compared to g-CN alone. The nanocomposites achieved a 98% removal rate of methyl orange under xenon lamp irradiation (>400 nm) for 1 hour.
View Article and Find Full Text PDFTalanta
December 2024
Department of Chemistry, University of Texas at San Antonio, TX, 78249, USA. Electronic address:
Aminated carbon nanotubes, CNT, were covalently modified with glutardialdehyde (GDI) and the redox dye Azure to form a new electrode material CNT-GDI-Azure (CGA). The nanocomposite of CGA and polysaccharide chitosan was used for the anodic determination of NADH. Compared to conventional carbon and metal electrodes, the CGA electrode drastically lowered the overpotential for NADH oxidation (by > 0.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
Department of Chemistry, Fu Jen Catholic University, New Taipei City 24205, Taiwan.
A novel metal-organic framework (MOF), (Cu-S)MOF, with a copper-sulfur planar structure was applied to photocatalytic H production application. (Cu-S)MOF@ZnS nanocomposite was synthesized using a microwave-assisted hydrothermal approach. The formation of (Cu-S)MOF and wurtzite ZnS in the composite nanoparticles was analyzed by X-ray diffraction (XRD), field emission-scanning electron microscopy (FESEM), and high-resolution transmission electron microscope (HRTEM).
View Article and Find Full Text PDFMikrochim Acta
December 2024
Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan, 411105, People's Republic of China.
GO/Co-MOF/PPy-350 (GPC-350) was synthesized by in situ growth of ultrafine Co-MOF on graphene oxide (GO), followed by encapsulation with polypyrrole (PPy) and calcination at 350.0℃. Meanwhile, MoS-MWCNTs (MoS-CNTs) were produced via the in situ synthesis of MoS within multi-walled carbon nanotubes (MWCNTs).
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
City University of Hong Kong, Department of Physics and Materials Science, 83 Tat Chee Ave, Kowloon Tong, 999077, Hong Kong, HONG KONG.
Redox-active covalent organic frameworks (COFs) have been demonstrated as promising organic electrodes in many electrochemical devices. However, their inherently low conductivity significantly hinders the full utilization of their internal redox-active sites. To address this issue, a simple solvothermal method is used to in situ polymerize 2,4,6-triformylphloroglucinol (TP) and p-phenylenediamine (PA) on the surface of carbon nanotubes (CNTs), generating a nanocable-like COF-based nanocomposite, TpPa-COF@CNT nanocables, which contain abundant β-ketoenamine groups.
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