Preparation and mechanism research of Ni-Co supported catalyst on hydrogen production from coal pyrolysis.

The combustible gas produced by coal pyrolysis can be used as a clean fuel to reduce environmental pollution caused by coal combustion. In order to improve the efficiency of coal pyrolysis to prepare flammable gases, Ni-Co supported pyrolysis catalysts were prepared by equal volume impregnation method using the pyrolysis coke of different pyrolysis final temperatures as the carrier in this study. The effects of different pyrolysis final temperatures and different metal loadings on pyrolysis products were studied. The cracking mechanism of the catalysts was characterized by BET, XRD, XPS and SEM. The results show that: (1) the catalytic efficiency of pyrolysis coke catalyst is mainly related to the metal type and loading of the additive. (2) The optimum preparation conditions for the supported catalyst are: use pyrolysis coke with 750 °C final pyrolysis temperature as the carrier, the loading amount of Ni is 5%, and the loading amount of Co is 8%.