We propose the idea of a spin-lattice liquid, in which spin and lattice degrees of freedom are strongly coupled and remain disordered and fluctuating down to low temperatures. We show that such a state arises naturally from a microscopic analysis of a class of molybdate pyrochlore compounds, and is driven by a giant magnetoelastic effect. Finally, we argue that this could explain some of the experimental features of Y_{2}Mo_{2}O_{7}.
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http://dx.doi.org/10.1103/PhysRevLett.122.227202 | DOI Listing |
J Phys Chem B
January 2025
Department of Physics and Biophysics, University of Warmia and Mazury in Olsztyn, Oczapowskiego 4, Olsztyn 10-719, Poland.
H and F spin-lattice relaxation experiments have been performed for a series of ionic liquids: [HMIM][TFSI], [OMIM][TFSI], and [DMIM][TFSI] including the same anion and cations with progressively longer alkyl chains. The experiments were performed in a wide frequency range from 10 kHz to 10 MHz (referring to the H resonance frequency) versus temperature. This extensive data set has been analyzed in terms of a theoretical model including all relevant homonuclear (H-H and F-F) and heteronuclear (H-F) relaxation pathways and linking the relaxation features to the relative translational diffusion between the ion pairs (cation-cation, cation-anion, and anion-anion).
View Article and Find Full Text PDFChem Sci
December 2024
Department of Chemistry, University of Copenhagen DK-2100 Copenhagen Denmark
We probe herein the fundamental factors that induce decoherence in ensembles of molecular magnetic materials. This is done by pulse Electron Paramagnetic Resonance measurements at X-band (∼9.6 GHz) on single crystals of Gd@Y(trensal) at 0.
View Article and Find Full Text PDFJ Chem Phys
November 2024
Department of Physics and Biophysics, University of Warmia and Mazury in Olsztyn, Oczapowskiego 4, 10-719 Olsztyn, Poland.
1H spin-lattice relaxation experiments have been performed for ionic liquid-polymer gel membranes, including 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF4]) and poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP) with different proportions. The experiments have been performed in a broad range of resonance frequencies (from about 5 Hz to 40 MHz) vs temperature and complemented with analogous studies for [BMIM][BF4] in bulk as a reference. A model of the relaxation processes in the membranes has been proposed.
View Article and Find Full Text PDFJ Mol Model
September 2024
Center for Computational Quantum Chemistry, University of Georgia, Athens, GA, 30602, USA.
Context: 2,2,2-Trifluoroethanol (TFE) is known as a membrane mimetic solvent. The IR spectrum, H NMR spectrum, C NMR spin‒lattice relaxation times (T), and nuclear Overhauser effect (NOE) data are consistent with extensive hydrogen bonding in TFE, but do not lead to structural features of the hydrogen bonding. Hence, DFT computations were carried out.
View Article and Find Full Text PDFNat Commun
August 2024
Technical University of Munich, TUM School of Natural Sciences, Physics Department, Garching, Germany.
Quantum fluctuations can inhibit long-range ordering in frustrated magnets and potentially lead to quantum spin liquid (QSL) phases. A prime example are gapless QSLs with emergent U(1) gauge fields, which have been understood to be described in terms of quantum electrodynamics in 2+1 dimension (QED). Despite several promising candidate materials, however, a complicating factor for their realisation is the presence of other degrees of freedom.
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