A composite polymer, hydroxyapatite/poly(acrylamide-acrylic acid), was synthesized by gamma-induced polymerization. The factors affecting the sorption process were evaluated. The removal increased with time and achieved equilibrium after 1 h for all initial concentration ranges (10-50 mg/L). The highest removal of Sr(II) was achieved using 50 mg/L at pH 6. The sorption process was found to follow a pseudo-first-order mechanism. The equilibrium data are best described by the Langmuir model, with a monolayer capacity of 53.59 mg/g. The values of thermodynamic parameters indicate that the sorption process is endothermic (ΔH > 0), increases randomness (ΔS > 0) and is spontaneous (ΔG < 0). The results imply that the composite could be used as a promising low-cost material for the removal of radionuclides from radioactive waste.
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http://dx.doi.org/10.1007/s11356-019-05755-1 | DOI Listing |
Water Res
December 2024
Department of Civil and Environmental Engineering, University of California, Berkeley, CA, 94720, United States. Electronic address:
Military bases and airports are often contaminated by per- and polyfluoroalkyl substances (PFAS) due to the repeated use of aqueous film forming foams (AFFFs) from decades of training exercises, equipment testing, and extinguishing of fuel- and solvent-based fires. Pump-and-treat systems combined with sorption processes are common ex situ remediation strategies; however, they can be expensive and may require decades of operation, particularly at sites where long-term diffusion and desorption of contaminants are the primary release processes. Alternatively, in situ chemical oxidation is an effective remediation strategy in which oxidants (e.
View Article and Find Full Text PDFArch Environ Contam Toxicol
December 2024
ExxonMobil Biomedical Sciences, Inc., 1545 US Highway 22 East, Annandale, NJ, 08801-3059, USA.
Environmental risk assessments of very hydrophobic organic compounds (VHOCs) in soils are often difficult because multiple processes (e.g., sorption, volatilization, biodegradation) can complicate the interpretation of results.
View Article and Find Full Text PDFEnviron Technol
December 2024
Worley Consulting, Fort Collins, CO, USA.
Treatment wetlands have emerged as a potential remediation option for oil-sands process affected waters (OSPW) which contains a suite of organic and inorganic constituents of potential concern. The aim of this study was to evaluate the fate of metals in a treatment wetland exposed to OSPW. Data was collected over three operational seasons testing freshwater and OSPW inputs at the Kearl Treatment Wetland in northern Alberta.
View Article and Find Full Text PDFChemosphere
December 2024
Bursa Technical University, Department of Environmental Engineering, Bursa, Türkiye. Electronic address:
The pollution potential of a municipal wastewater treatment plant (WWTP) in Bursa, Türkiye, in terms of organochlorine pesticides (ΣOCPs), polychlorinated biphenyls (ΣPCBs), and polybrominated diphenyl ethers (ΣPBDEs), was investigated in air samples. Concentrations were determined using polyurethane foam disk samplers at key processes, such as the aeration tank (AT) and settling chamber (SC) of the WWTP and the background area (BA) at an urban site. Atmospheric concentration levels of PBDEs at the SC are 1.
View Article and Find Full Text PDFFood Chem
December 2024
School of Food and Biological Engineering, Key Laboratory of Modern Agricultural Products Processing of Anhui Province, Hefei University of Technology, Hefei 230601, China. Electronic address:
Plant protein-stabilized Pickering nanoemulsions show potential as plant-based milk substitutes; however, their stability is challenged by mechanical stress during transportation and oxidative deterioration during storage. Herein, soybean isolate protein-curcumin composite nanoparticle (SPI-Cur-NPs)-stabilized Pickering nanoemulsions were converted into microcapsule powders via spray-drying with maltodextrin (MD), trehalose anhydrous (TA), and inulin (IN) as wall materials. Robust intermolecular hydrogen bonds and an amorphous structure were formed using composite wall materials, reducing microcapsule surface fissures while improving encapsulation rate (92.
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