We reported a microporous MOF FJU-101 with open naphthalene diimide functional groups for room temperature (RT) high methane storage. At RT and 65 bar, the total volumetric CH storage capacity of 212 cm (STP) cm of FJU-101a is significantly higher than those of the isoreticular MFM-130a and UTSA-40a. The enhanced methane uptake in FJU-101a is attributed to the polar carbonyl sites, which can generate strong electrostatic interactions with CH molecules.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7974511 | PMC |
| http://dx.doi.org/10.1039/c9dt01911a | DOI Listing |
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