A new robust Bi-carboxylate metal-organic framework (MOF) IEF-2 was hydrothermally prepared, acting as a proton carrier (σ∼ 1.1 × 10 S cm). Such proton conductivity is among the highest reported so far for purely 3D carboxylate-based MOFs, being explained by the existence of a 1D hydrogen-bond network, as suggested by structural analysis and theoretical studies.
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A new proton-conducting Bi-carboxylate framework.
Dalton Trans
August 2019
Advanced Porous Materials Unit (APMU), IMDEA Energy Institute, Avda. Ramón de la Sagra 3, E-28938 Móstoles, Madrid, Spain.
A new robust Bi-carboxylate metal-organic framework (MOF) IEF-2 was hydrothermally prepared, acting as a proton carrier (σ∼ 1.1 × 10 S cm). Such proton conductivity is among the highest reported so far for purely 3D carboxylate-based MOFs, being explained by the existence of a 1D hydrogen-bond network, as suggested by structural analysis and theoretical studies.
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