Many applications require charge neutralization of isolated test bodies, and this has been successfully done using photoelectric emission from surfaces which are electrically benign (gold) or superconducting (niobium). Gold surfaces nominally have a high work function (∼5.1 eV) which should require deep UV photons for photoemission. In practice, it has been found that it can be achieved with somewhat lower energy photons with indicative work functions of (4.1-4.3 eV). A detailed working understanding of the process is lacking, and this work reports on a study of the photoelectric emission properties of 4.6 × 4.6 cm gold plated surfaces, representative of those used in typical satellite applications with a film thickness of 800 nm, and measured surface roughnesses between 7 and 340 nm. Various UV sources with photon energies from 4.8 to 6.2 eV and power outputs from 1 nW to 1000 nW illuminated ∼0.3 cm of the central surface region at angles of incidence from 0° to 60°. Final extrinsic quantum yields in the range 10 ppm-44 ppm were reliably obtained during 8 campaigns, covering a period of ∼3 years but with intermediate long-term variations lasting several weeks and, in some cases, bake-out procedures at up to 200 °C. Experimental results were obtained in a vacuum system with a baseline pressure of ∼10 mbar at room temperature. A working model, designed to allow accurate simulation of any experimental configuration, is proposed.
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http://dx.doi.org/10.1063/1.5088135 | DOI Listing |
Inorg Chem
December 2024
Department of Energy and Materials, Kindai University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502 Japan.
Three distinct n-type semiconductors were derived from a platinum-trialkyl phosphine complex; to lower their LUMO levels, various indene derivatives were incorporated using thiophene (PtTIC ()), thieno[3,2-]thiophene (PtT2IC ()), and 4-cyclopenta[2,1-:3,4-']dithiophene (PtCDTIC ()) as the acetylide donor units. Single-crystal X-ray diffractometry analysis revealed translinear platinum-acetylide complexation in all cases. The strong (═O···S) interactions between the oxygen atoms of the indene acceptor units and the sulfur atoms of the thiophene-derived donor units induced a highly planar orientation among the heterocyclic ligands, featuring π-π interactions between the planes.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
College of Physics and Optoelectronics, Taiyuan University of Technology, Taiyuan 030024, China.
Composition-adjustable semiconductor nanomaterials have garnered significant attention due to their controllable bandgaps and electronic structures, providing alternative opportunities to regulate photoelectric properties and develop the corresponding multifunction optoelectronic devices. Nevertheless, the large-scale integration of semiconductor nanomaterials into practical devices remains challenging. Here, we report a synthesis strategy for the well-aligned horizontal CdSSe ( = 0-1) nanowall arrays, which are guided grown on an annealed M-plane sapphire using chemical vapor deposition (CVD) approaches.
View Article and Find Full Text PDFSensors (Basel)
December 2024
College of Physics and Electronic Engineering, Hainan Normal University, Haikou 571158, China.
This study explores the fabrication of ZnO-SiO composite films on silicon substrates via a sol-gel method combined with spin-coating, followed by annealing at various temperatures. The research aims to enhance the UV emission and photoelectric properties of the films. XRD showed that the prepared ZnO sample has a hexagonal structure.
View Article and Find Full Text PDFAdv Mater
December 2024
Shaanxi Joint Lab of Graphene, State Key Lab Incubation Base of Photoelectric Technology and Functional Materials, International Collaborative Center on Photoelectric Technology and Nano Functional Materials, Institute of Photonics & Photon-Technology, Northwest University, Xi'an, 710069, P. R. China.
Bulk photovoltaic effect (BPVE) can break the Shockley-Queisser limit by leveraging the inherent asymmetry of crystal lattice without a junction. However, this effect is mainly confined to UV-vis spectrum due to the wide-bandgap nature of traditional ferroelectric materials, thereby limiting the exploration of the infrared light-driven efficient BPVE. Herein, giant two-photon absorption (TPA) driven BPVE is uncovered from visible to infrared in ferroelectric α-InSe utilizing wavelength-tunable terahertz (THz) emission spectroscopy.
View Article and Find Full Text PDFNanotechnology
December 2024
Laser Institute, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250014, People's Republic of China.
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