The paper proposes a fully optical method for determination of a cubic crystal grain orientation in a sample inspected by a Raman microscope. The method is based on a universal and strong polarisation anisotropy of the Raman scattering by doubly degenerate optic phonon modes and it only requires a standard Raman microscope equipped with a polarisation analysis. Explicit formulas for the orientation of the crystal grain are derived. The feasibility of the approach is demonstrated by comparing grain orientations in a polycrystalline cubic lacunar spinel GaVS determined independently using electron backscatter diffraction and Raman scattering methods.
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http://dx.doi.org/10.1038/s41598-019-45782-z | DOI Listing |
Anal Chim Acta
February 2025
Engineering Research Center of Optical Instrument and System, Ministry of Education and Shanghai Key Lab of Modern Optical System, University of Shanghai for Science and Technology, No.516 Jungong Road, Shanghai, 200093, China.
Background: Surface-enhanced Raman scattering (SERS) has attracted much attention as a powerful detection and analysis tool with high sensitivity and fast detection speed. The intensity of the SERS signal mainly depended on the highly enhanced electromagnetic field of nanostructure near the substrate. However, the fabrication of high-quality SERS nanostructured substrates is usually complicated, makes many methods unsuitable for large-scale production of SERS substrates.
View Article and Find Full Text PDFAnal Chim Acta
February 2025
The Key Laboratory of Biomedical Information Engineering of Ministry of Education, School of Life Science and Technology, Xi'an Jiaotong University, No. 28 Xianning West Road, Xi'an, 710049, China. Electronic address:
Background: Plasmonic core-shell nanostructures with embedded internal markers used as Raman probes have attracted great attention in surface-enhanced Raman scattering (SERS) immunoassay for cancer biomarkers due to their excellent uniform enhancement. However, current core-shell nanostructures typically exhibit a spherical shape and are coated with a gold shell, resulting in constrained local field enhancement.
Results: In this work, we prepared a core-shell AuNR@BDT@Ag structure by depositing silver on the surface of Raman reporter-modified gold nanorods (AuNR).
J Colloid Interface Sci
January 2025
College of Light Industry and Food Engineering, Nanjing Forestry University, Jiangsu Co-Innovation Center for Efficient Processing and Utilization of Forest Resources, Nanjing 210037 China. Electronic address:
Surface-enhanced Raman scattering (SERS) is a highly sensitive technology to detect target analytes. The construction of dynamic "hot-spots" represents a significant approach to enhancing detection sensitivity. Herein, a hybrid plasma platform with dynamic "hot-spots" was developed for SERS recognition based on the assembly of gold nanospheres (AuNSs) on temperature-sensitive bacterial cellulose (BC) film grafted with poly(N-isopropylacrylamide) (PNIPAM).
View Article and Find Full Text PDFForensic Sci Int
January 2025
Departamento de Química. Faculdade de Filosofia, Ciências e Letras de Ribeirão Preto. Universidade de São Paulo, Avenida Bandeirantes, 3900, Ribeirão Preto, São Paulo CEP 14040-901, Brazil; Instituto Nacional de Ciência e Tecnologia Ciências Forenses (INCT-Forense), Departamento de Química, Faculdade de Filosofia Ciências e Letras de Ribeirão Preto, Universidade de São Paulo, Ribeirão Preto, SP 14040-901, Brasil; Programa de Cooperação Acadêmica - Segurança Pública e Ciências Forenses (PROCAD-SPCF), Departamento de Química, Faculdade de Filosofia Ciências e Letras de Ribeirão Preto, Universidade de São Paulo, Ribeirão Preto, SP 14040-901, Brasil. Electronic address:
Forensic gemstone analysis faces many challenges. One of the most critical aspects of gemological research is the classification of a gemstone. It is necessary to understand the mineral species, purity, origin, and identification of treatments to identify and classify a gem correctly, as well as assign a monetary value to it.
View Article and Find Full Text PDFAnal Bioanal Chem
January 2025
European Commission, Joint Research Centre (JRC), Geel, Belgium.
When performing effect studies to investigate the impact of microplastic (MP) on cell lines, algae, or daphnia, it is advantageous if such experiments can be performed without the use of surfactants. The need for surfactants arises from the fact that finely milled pristine MP particles generally are hydrophobic. Methods for the preparation of larger amounts of hydrophilic and hence artificially aged MP particles and approaches for their characterization are of high importance.
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