Birefringent crystals with optical anisotropy, which are employed to modulate the polarization of light, play a vital role in many fields of the optical industry. In this Communication, two mixed alkali metal hydroisocyanurates, RbLi(HCNO)·2HO () and CsLi(HCNO)·2HO (), were synthesized by a simple aqueous solution method, and they feature layered structures composed of [HCNO] ribbons through hydrogen bonds with the separation of water molecules and alkali cations. They exhibit a simultaneously short ultraviolet cutoff and giant birefringence, resulting from the perfect parallel alignment of π-conjugated (HCNO) anions. Interestingly, the first-principles calculations elucidated that the electronic states and optical properties are slightly different owing to the distinct p-π interaction between alkaline metals and the (HCNO) group despite the isostructural crystallographic lattice.
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| http://dx.doi.org/10.1021/acs.inorgchem.9b01646 | DOI Listing |
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