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Thymine-Hg-thymine coordination chemistry induced entropy driven catalytic reaction to form Hemin/G-quadruplex-HRP-mimicking DNAzyme for colorimetric and visual determination of Hg. | LitMetric

AI Article Synopsis

Article Abstract

A sensitive and visible colorimetric strategy was proposed for Hg detection by thymine-Hg-thymine (T-Hg-T) coordination chemistry and entropy driven catalytic reaction. The entropy driven catalytic reaction is induced by T-Hg-T coordination chemistry, resulting the releasing of G-riched sequence. Hemin/G-quadruplex-HRP-mimicking DNAzyme can be formed with the help of hemin, catalyzing TMB to TMB with a color change from colorless to blue. The sensitivity of this strategy can be reached to 2 pM, which is significantly improved by entropy driven catalytic reaction. In addition, entropy driven catalytic reaction provides a more reliable and accurate results. This method shows great promise for on-site analysis and in-house diagnosis of Hg in water.

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http://dx.doi.org/10.1016/j.saa.2019.117228DOI Listing

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