We investigate time-resolved charge transport through graphene nanoribbons supplemented with adsorbed impurity atoms. Depending on the location of the impurities with respect to the hexagonal carbon lattice, the transport properties of the system may become invisible to the impurity due to the symmetry properties of the binding mechanism. This motivates a chemical sensing device since dopants affecting the underlying sublattice symmetry of the pristine graphene nanoribbon introduce scattering. Using the time-dependent Landauer-Büttiker formalism, we extend the stationary current-voltage picture to the transient regime, where we observe how the impurity invisibility takes place at sub-picosecond time scales further motivating ultrafast sensor technology. We further characterize time-dependent local charge and current profiles within the nanoribbons, and we identify rearrangements of the current pathways through the nanoribbons due to the impurities. We finally study the behavior of the transients with ac driving which provides another way of identifying the lattice-symmetry breaking caused by the impurities.
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http://dx.doi.org/10.1039/c9nr02738f | DOI Listing |
Polymers (Basel)
January 2025
Department of Chemical Engineering, Dr B R Ambedkar National Institute of Technology, Jalandhar 144011, Punjab, India.
Antimicrobial polymeric coatings rely not only on their surface functionalities but also on nanoparticles (NPs). Antimicrobial coatings gain their properties from the addition of NPs into a polymeric matrix. NPs that have been used include metal-based NPs, metal oxide NPs, carbon-based nanomaterials, and organic NPs.
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January 2025
Departamento de Química Orgánica, Universidad de Zaragoza, 50009 Zaragoza, Spain.
Dye-sensitization is a promising strategy to improve the light absorption and photoactivity abilities of wide-bandgap semiconductors, like TiO. For effective water-splitting photoanodes with no sacrificial agents, the electrochemical potential of the dye must exceed the thermodynamic threshold needed for the oxygen evolution reaction. This study investigates two promising organic cyanoacrylic dyes, designed to meet that criterion by means of theoretical calculations.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
Faculty of Electrical, Electronic, Computer and Control Engineering, Lodz University of Technology, 18. Stefanowskiego Str., 90-924 Lodz, Poland.
Toxic materials are a threat in workplaces and the environment, as well as households. In them, gaseous substances are included, especially ones without any colour or fragrance, due to their non-detectability with the human senses. In this article, an attempt was made to find a solution for its detection in various conditions with the use of intelligent textiles.
View Article and Find Full Text PDFACS Nano
January 2025
Department of Chemistry, University of Chicago, Chicago, Illinois 60637, United States.
Fabricating organic semiconducting materials into large-scale, well-organized architectures is critical for building high-performance molecular electronics. While graphene nanoribbons (GNRs) hold enormous promise for various device applications, their assembly into a well-structured monolayer or multilayer architecture poses a substantial challenge. Here, we report the preparation of length-defined monodisperse GNRs via the integrated iterative binomial synthesis (IIBS) strategy and their self-assembly into submicrometer architectures with long-range order, uniform orientation, as well as regular layers.
View Article and Find Full Text PDFNanomaterials (Basel)
January 2025
School of Environment, Northeast Normal University, Changchun 130117, China.
The disinfection of drinking water is essential for eliminating pathogens and preventing waterborne diseases. However, this process generates various disinfection byproducts (DBPs), which toxicological research indicates can have detrimental effects on living organisms. Moreover, the safety of these DBPs has not been sufficiently assessed, underscoring the need for a comprehensive evaluation of their toxic effects and associated health risks.
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