Reconfigurable plasmon-based flexible devices, composed of artificial plasmonic nanostructures on stretchable substrates, show great promise for dynamic functionalities such as tunability, switching and modulation of electromagnetic waves. Here, we theoretically proposed and experimentally demonstrated a simple and efficient flexible plasmonic modulator based on an array of gold nanostructures on a poly(dimethylsiloxane) (PDMS) substrate. Arising from the current-induced local Joule heat, the local expansion of the PDMS substrate widens the gap distances between the neighboring gold wires, which results in a spectral shift of the plasmon resonance. The experimental results show that the plasmon resonance has a blue-shift of 39 nm under a total power consumption of only 10.5 mW, which results in a high modulation depth of up to 30.5% for the modulator. Such a low power consumption can be ascribed to the small active area and excellent thermal isolation of the PDMS. The optical and thermomechanical responses were confirmed and understood by the electromagnetic and thermomechanical co-simulations based on the finite-difference time-domain and finite-element methods. This novel mechanism to manipulate light provides new opportunities for active optical components and integrated circuits.
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http://dx.doi.org/10.1039/c9nr04068d | DOI Listing |
Food Chem
January 2025
School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China.
Carbaryl is a broad-spectrum carbamate fungicide that may pose a threat to ecosystems and human health. To prevent and control the harm caused by excessive application of carbaryl, a full-dimensional divergence effect SERS sensor has been constructed. Biodegradable paper chips were used as sensor substrates.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
Department of Chemical Engineering, Ataturk University, 25240 Erzurum, Turkey.
The combination of plasmonic metals and MXene, as a new and interesting member of the 2D material class, may provide unique advantages in terms of low cost, versatility, flexibility, and improved activity as an ideal surface-enhanced Raman spectroscopy (SERS) platform. Despite the recent progress, the present studies on the utilization of plasmonic metal/MXene-based SERS systems are quite limited and thereby benefits of the extraordinary properties of this combination cannot be realized. In this study, for the first time, we propose layer-by-layer (LbL) thin films of TiC MXene and gold nanoparticles (AuNPs) as a robust SERS platform (TiC/AuNPs).
View Article and Find Full Text PDFPolymers (Basel)
December 2024
Hainan Engineering Research Center of Tropical Ocean Advanced Opto-Electrical Functional Materials, College of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, China.
Chrysoidin (CG) can be ingested into the human body through the skin and cause chronic toxicity, so the detection of CG levels in the environment is crucial. In this study, we synthesize F-Ag@ZIF-8/PVC molecular-imprinted membranes (FZAP-MIM) by an innovative combination of SERS detection, membrane separation, and a molecular-imprinted technique in order to perform the analysis of CG in water. The plasmonic MOF material as a SERS substrate helps to enrich the target and realize the spatial overlap of the target with the nanoparticle tip "hotspot".
View Article and Find Full Text PDFSci Rep
January 2025
Photonics Research Centre, Universiti Malaya, Kuala Lumpur, 50603, Malaysia.
Two-dimensional (2D) hexagonal boron nitride (hBN) has garnered significant attention due to its exceptional thermal and chemical stability, excellent dielectric properties, and unique optical characteristics, making it widely used in deep ultraviolet (DUV) applications. However, the integration of hBN with plasmonic materials in the visible region (532 nm) has not been fully explored, particularly in terms of morphology regulation and size control of mono- and bimetallic nanoparticles (BMNPs) namely gold (Au), silver (Ag) and Au-Ag. A Schottky junction-based metal-semiconductor contact configuration is employed to achieve hot-carrier reflections on the metal side, enhancing the quantum efficiency of the photodetector.
View Article and Find Full Text PDFJ Gen Physiol
January 2025
Chemistry Department, University of Massachusetts Lowell, Lowell, MA, USA.
Titin is the third contractile filament in the sarcomere, and it plays a critical role in sarcomere integrity and both passive and active tension. Unlike the thick and thin filaments, which are polymers of myosin and actin, respectively, titin is a single protein that spans from Z-disk to M-line. The N2A region within titin has been identified as a signaling hub for the muscle and is shown to be involved in multiple interactions.
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