Double metal cyanides (DMCs) are well known, industrially applied catalysts for ring opening polymerization reactions. In recent years, they have been studied for a variety of catalytic reactions, as well as other applications, such as energy storage and Cs sorption. Herein, a new, layered DMC phase (), Zn[Co(CN)](CHCOO)·4HO, was synthesized. The structure, which crystallizes in the monoclinic space group 2/, consists of positively charged {ZnCo(CN)} DMC layers linked through acetate groups and presents a new layered structure to the family of double metal cyanides. proved to be a reusable and stable catalyst that exhibited a higher activity than the benchmark DMC catalyst in two important applications: hydroamination of phenylacetylene with 4-isopropylaniline and polymerization of 1,2-epoxyhexane.
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| http://dx.doi.org/10.1039/c9sc00527g | DOI Listing |
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