We present the photoelectron spectroscopy of the simplest Criegee intermediate, CHOO, close to the first ionization energy. Comparison with existing theoretical data yields the experimental adiabatic ionization energy and provides a benchmark for theoretical studies on larger Criegee intermediates, which play an important role in the ozonolysis of alkenes.
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| http://dx.doi.org/10.1039/c9cp02538c | DOI Listing |
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