Atomic layer deposition (ALD) is an ultra-thin film deposition technique that has found many applications owing to its distinct abilities. They include uniform deposition of conformal films with controllable thickness, even on complex three-dimensional surfaces, and can improve the efficiency of electronic devices. This technology has attracted significant interest both for fundamental understanding how the new functional materials can be synthesized by ALD and for numerous practical applications, particularly in advanced nanopatterning for microelectronics, energy storage systems, desalinations, catalysis and medical fields. This review introduces the progress made in ALD, both for computational and experimental methodologies, and provides an outlook of this emerging technology in comparison with other film deposition methods. It discusses experimental approaches and factors that affect the deposition and presents simulation methods, such as molecular dynamics and computational fluid dynamics, which help determine and predict effective ways to optimize ALD processes, hence enabling the reduction in cost, energy waste and adverse environmental impacts. Specific examples are chosen to illustrate the progress in ALD processes and applications that showed a considerable impact on other technologies.
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http://dx.doi.org/10.1080/14686996.2019.1599694 | DOI Listing |
Phys Rev Lett
December 2024
Institute of Molecular Science, University of Valencia, Catedratico Jose Beltrán 2, 46980 Paterna, Spain.
The role of self-intercalation in 2D van der Waals materials is key to the understanding of many of their properties. Here we show that the magnetic ordering temperature of thin films of the 2D ferromagnet Fe_{5}GeTe_{2} is substantially increased by self-intercalated Fe that resides in the van der Waals gaps. The epitaxial films were prepared by molecular beam epitaxy and their magnetic properties explored by element-specific x-ray magnetic circular dichroism that showed ferromagnetic ordering up to 375 K.
View Article and Find Full Text PDFNanoscale
January 2025
Department of Materials Science and Engineering, Chair for Surface Science and Corrosion (WW4-LKO), Friedrich-Alexander-Universität Erlangen-Nürnberg, Martensstraße 7, 91058 Erlangen, Germany.
The photocatalytic degradation of unwanted organic species has been investigated for decades using modified and non-modified titania nanostructures. In the present study, we investigate the co-catalytic effect of single atoms (SAs) of Pt and Pt nanoparticles on titania substrates on the degradation of the two typical photodegradation model pollutants: Acid Orange 7 (AO7) and Rhodamine B (RhB). For this, we use highly defined sputter deposited anatase layers and load them with Pt SAs at different loading densities or alternatively with Pt nanoparticles.
View Article and Find Full Text PDFMater Horiz
January 2025
Department of Chemical Engineering, Stanford University, Stanford, California 94305, USA.
In recent years, area-selective deposition (ASD) processes have attracted increasing interest in both academia and industry due to their bottom-up nature, which can simplify current fabrication processes with improved process accuracy. Hence, more research is being conducted to both expand the toolbox of ASD processes to fabricate nanostructured materials and to understand the underlying mechanisms that impact selectivity. This article provides an overview of current developments in ASD processes, beginning with an introduction to various approaches to achieve ASD and the factors that affect selectivity between growth and non-growth surfaces, using area-selective atomic layer deposition (AS-ALD) as the main model system.
View Article and Find Full Text PDFAdv Mater
January 2025
School of Electronic and Computer Engineering, Peking University, Shenzhen, 518055, China.
The increasing demand for mobile artificial intelligence applications has elevated edge computing to a prominent research area. Silicon materials, renowned for their excellent electrical properties, are extensively utilized in traditional electronic devices. However, the development of silicon materials for flexible neuromorphic computing devices encounters great challenges.
View Article and Find Full Text PDFInorg Chem
January 2025
Bordeaux INP, ICMCB, UMR 5026, Université de Bordeaux, CNRS, F-33600 Pessac, France.
LiCoPO and LiNiPO phosphate pigments have colorations very close to the primary colors of the subtractive system: magenta and yellow, respectively. These two pigments are therefore of great interest in a variety of applications, including e-reader devices. However, the need to reduce their crystallite size in order to formulate stable electrophoretic inks has revealed that aggressive milling results in significant color changes, particularly for cobalt-based pigments.
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