Oxo-bridged trimeric chromium acetate clusters [Cr O(OOCCH ) (H O) ]NO have been encapsulated for the first time in the mesoporous cages of the chromium terephthalate MIL-101(Cr). The isolated clusters in MIL-101(Cr) have increased affinity towards propylene compared to propane, due to generation of a new kind of pocket-based propylene-binding site, as supported by DFT calculations.
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| http://dx.doi.org/10.1002/chem.201902249 | DOI Listing |
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