A new antifluorite-type (LiO-type) cubic compound, VSe, has been synthesized for the first time by changing the amount of selenium in chemical vapor transport. The vanadium-based cubic phase studied here reveals a metal-metal bonding feature in the electronic band structure. This compound is the first example of an antifluorite-type cubic structure in a V-Se system.
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| http://dx.doi.org/10.1039/c9dt01569h | DOI Listing |
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