For the low-concentration oily micro-polluted water formed by the leakage of refined oil products, an unexpensive and high-efficiency magnetic enhanced flocculation method was introduced in this study. First, the performance of magnetic flocculation(MF) to remove oily contaminants was discussed. The results indicated that it achieved more than 95% removal in only 1min with 50mg/L-Polyaluminum chloride(PAC), 50mg/L-FeO and10mg/L- Polyacrylamide (PAM). The novel indexs Rand S were proposed to evaluate the oil removal with UV-Abs in-situ method. According to the adsorption kinetics of oil contaminants, the adsorption kinetics changed from pseudo-first-order to pseudo-second-order kinetics after the addition of FeO on the basis of conventional coagulation (CF). It was transformed into intraparticle diffusion kinetics when the PAM continued to be added. Combined with the Fe-O-Al bond in the FTIR spectrum of flocs, the main mechanism of MF is enhanced charge neutralization and hydrogen bond adsorption. In addition, it was shown that satisfactory oil removal after recover, which indicated the great potential of a sustainable way by reusing low-cost magnetic seeds.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1016/j.jenvman.2019.05.068 | DOI Listing |
J Environ Manage
August 2019
School of Environmental Science and Engineering, Tianjin Polytechnic University, Tianjin, 300387, China.
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!