Poly (Lactic Acid), PLA, and Poly (ε-CaproLactone), PCL, compatibilized with Ethyl Ester l-Lysine Triisocyanate (LTI) can be employed as biomaterials. We mixed PLA with PCL and LTI in a twin extruder and by a melt spinning process obtained threads with an average diameter of about 0.3 mm. In order to study the possible application of these threads, mechanical tensile (with the calorimetric and morphological investigations) and biological tests were performed. The results highlighted these biopolymers as promising materials for sutures since they can be rigid and elastic (especially by increasing the PCL amount in the blend), and they are bioactive, able to inhibit bacterial growth. This paper represents a starting point to optimize the blend composition for biomedical suture application.
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http://dx.doi.org/10.3390/polym11050901 | DOI Listing |
Sensors (Basel)
November 2024
École Nationale Supérieure des Arts et Industries Textiles-ENSAIT, ULR 2461-GEMTEX-Génie et Matériaux Textiles, University of Lille, F-59000 Lille, France.
Women sports wearer's comfort and health are greatly impacted by the breast movements and resultant sports bra compression to prevent excessive movement. However, as sports bras are only made in universal sizes, they do not offer the right kind of support that is required for a certain activity. To prevent this issue, textile-based strain sensors may be utilized to track compression throughout various activities to create activity-specific designed sports bras.
View Article and Find Full Text PDFSoft Matter
November 2024
Department of Physics and Biophysics, University of San Diego, 5998 Alcala Park, San Diego, CA 92110, USA.
Blends of circular and linear polymers have fascinated researchers for decades, and the role of topology on their stress response and dynamics remains fervently debated. While linear polymers adopt larger coil sizes and form stronger, more pervasive entanglements than their circular counterparts, threading of circular polymers by linear chains can introduce persistent constraints that dramatically decrease mobility, leading to emergent rheological properties in blends. However, the complex interplay between topology-dependent polymer overlap and threading propensity, along with the large amounts of material required to sample many compositions, has limited the ability to experimentally map stress response to composition with high resolution.
View Article and Find Full Text PDFPhys Rev Lett
September 2024
Sandia National Laboratories, Albuquerque, New Mexico 87185, USA.
Polymers are an effective test bed for studying topological constraints in condensed matter due to a wide array of synthetically available chain topologies. When linear and ring polymers are blended together, emergent rheological properties are observed as the blend can be more viscous than either of the individual components. This emergent behavior arises since ring-linear blends can form long-lived topological constraints as the linear polymers thread the ring polymers.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2024
College of Polymer Science & Engineering, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, China.
Ocul Surf
October 2024
Huaxia Eye Hospital of Quanzhou, Quanzhou, Fujian, 362000, China; Eye Institute & Affiliated Xiamen Eye Center &The First Affiliated Hospital, School of Medicine, Xiamen University, Xiamen, Fujian, 361102, China; Fujian Provincial Key Laboratory of Ophthalmology and Visual Science, Xiamen, Fujian, 361102, China; Fujian Engineering and Research Center of Eye Regenerative Medicine, Xiamen, Fujian, 361102, China. Electronic address:
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