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[2.2]Paracyclophane bis(pyridine)-based metallosupramolecular rhombs in the gas phase: Competitive cleavage of non-covalent and weak covalent bonds. | LitMetric

[2.2]Paracyclophane bis(pyridine)-based metallosupramolecular rhombs in the gas phase: Competitive cleavage of non-covalent and weak covalent bonds.

J Am Soc Mass Spectrom

Kekulé-Institute of Organic Chemistry and Biochemistry, University of Bonn, Gerhard-Domagk-Str. 1, 53121, Bonn, Germany.

Published: October 2019

AI Article Synopsis

Article Abstract

The gas-phase fragmentation behavior of self-assembled metallo-supramolecular rhombs based on an unusual chiral [2.2]paracyclophane bis(pyridine) ligand is studied by collision-induced dissociation mass spectrometry. The fragmentation patterns strongly depend on the charge state of the respective mass-selected aggregate. For the doubly charged ions, simple symmetric fragmentation is observed in full accordance with previous results reported for related metallo-supramolecular species. The triply charged species cleaves unsymmetrically which can be rationalized by a preferred formation of ions with low charge density. CID of the quadruply charged rhomb reveals a complex fragmentation. Besides ligand oxidation to the radical cation, facile cleavage of the central covalently bound part of the [2.2]paracyclophane ligand takes place which is even preferred over rupture of the weak dative pyridine-Pd bond.

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Source
http://dx.doi.org/10.1007/s13361-019-02218-2DOI Listing

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