Polymers of intrinsic microporosity (PIM-1) have an appropriate pore size to reduce the solvation number of Li ions in electrolytes. This unique pore structure of PIM-1 as a solid interphase can suppress transport of solvent and consequently unwanted chemical reactions at the interface of anodes, thereby extending the cycle life of Li metal anodes.

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http://dx.doi.org/10.1039/c9cc01329fDOI Listing

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