In this study, hetero-two-dimensional correlation spectroscopy (hetero-2DCOS) combined with parallel factor analysis (PARAFAC) was employed to reveal the inner changes in the dissolved organic matter (DOM) components derived from soil amended with seven different composts. The dynamics of the four DOM components showed that the fluorescence peaks in each component varied in different directions during mineralization. Structural equation models (SEMs) demonstrated that the compost amendments changed the correlations of the total organic carbon (TOC), total nitrogen (TN), and bacterial community composition with DOM components and strengthened the cooperative function related to transformation of DOM components. The compost sources were further ranked as cabbage waste (CW) > chicken manure (CM), dairy cattle manure (DCM), tomato stem waste (TSW), peat (P) > municipal solid waste (MSW), sewage sludge (SS) by projection pursuit regression (PPR) analysis. It is helpful to improve the bioavailability of compost products to obtain composts with a particular function.
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http://dx.doi.org/10.1021/acs.jafc.9b01073 | DOI Listing |
Environ Res
January 2025
Institute of Surface-Earth System Science, Tianjin University, Tianjin, China. Electronic address:
Ecosystems in cold and arid regions, such as Dai Lake - a typical inland, salinized lake in the semi-arid region of northern China - face severe environmental challenges, including salinization and biodiversity loss. This study investigates the chemical composition of dissolved organic matter (DOM) and the structure of microbial communities in lake water and sediments, offering novel insights into the ecosystem's dynamics. In winter, DOM in the lake water is primarily derived from decaying plant and animal matter, while sediment DOM is predominantly associated with microbial activity.
View Article and Find Full Text PDFEur Psychiatry
January 2025
Collaborative Antwerp Psychiatric Research Institute (CAPRI), University of Antwerp, Antwerp, Belgium.
Background: Recent years show an exponential increased interest ("renaissance") in the use of psychedelics for the treatment of mental disorders and broader. Some of these treatments, such as psilocybin for depression, are in the process of formal regulation by regulatory bodies in the US (FDA) and Europe (EMA), and as such on the brink of real-world implementation. In the slipstream of these developments increasing commercial initiatives are taking shape.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
Research Institute for Environmental Innovation (Binhai, Tianjin), Tianjin 300450, PR China. Electronic address:
The speciation and mobility of arsenic (As) in waters are largely influenced by the colloids; however, the impacts of colloids with different molecular weights (MWs) in water fractions remain largely unknown. Herein, the surface water was fractionated into three colloidal fractions and truly dissolved fraction via cross-flow ultrafiltration. Total As (As(T)) presented mainly as As(V) and existed primarily in the truly dissolved fraction.
View Article and Find Full Text PDFEnviron Sci Technol
January 2025
School of Environmental Science and Engineering, Shanghai Engineering Research Center of Solid Waste Treatment and Resource Recovery, Shanghai Jiao Tong University, Shanghai 200240, China.
In landfill leachates containing complex dissolved organic matter (DOM), the link between individual DOM constituents and their inherent oxidizability is unclear. Here, we resolved the molecular signatures of DOM oxidized by OH/O using FT-ICR MS, thereby elucidating their oxidizability and resistance in concentrated leachates. The comprehensive gradual fragmentation of complex leachate DOM was then revealed through a modified machine-learning framework based on 43 key pathways during ozonation.
View Article and Find Full Text PDFWater Res
December 2024
State Key Laboratory of Environmental Criteria and Risk Assessment, and State Environmental Protection Key Laboratory of Simulation and Control of Groundwater Pollution, Chinese Research Academy of Environmental Sciences, Beijing 100012, China.
Dissolved organic matter (DOM) represents one of the most active elements in aquatic systems, whose fraction is engaged in chemical and biological reactions. However, fluorescence, molecular diversity and variations of DOM in groundwater systems with the alteration of surface water recharge remain unclear. Herein, Excitation-emission matrix (EEM) fluorescence spectroscopy and Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) combined with principal component coefficients, parallel factor analyses (PARAFAC) with two‒dimensional correlation spectroscopy (2D-COS) were applied in this study.
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