MX-type one-dimensional complexes [Pt(amp)Br][Pt(amp)Br](HSO)(SO)·13HO (3) and [Pt(amp)Br][Pt(amp)Br](HPO)·8HO (4) were synthesized as the first analogue containing only an aromatic in-plane ligand. The Pt-Br chain structures of 3 and 4 are stabilized by both the hydrogen-bond network along the chain and the π-stacking via intercalated Pt(iv) complexes. Structural and spectroscopic studies indicated that both 3 and 4 form the Pt(ii/iv) mixed valence state.
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| http://dx.doi.org/10.1039/c9dt00784a | DOI Listing |
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