Impact of the Bonding Sites at the Inner or Outer π-Bridged Positions for Non-Fullerene Acceptors.

Two A-π-D-π-A-type non-fullerene acceptors (IDT-TFIC and IDT-TFIC) with 5-hexylthienyl chains substituted at the inner and outer β-positions of the thiophene π-bridge have been designed, respectively. Impacts of varied positional modifications are systematically studied. By utilizing PBDB-T as the donor, polymer solar cells are constructed with these two molecules as acceptors. Power conversion efficiencies of 11.09 and 9.46% are acquired for IDT-TFIC- and IDT-TFIC-based devices, respectively. Our studies have demonstrated that the use of thiophene spacers carrying one conjugated side chain at different positions can markedly enhance the photovoltaic properties relative to the corresponding control molecule IDTT2F.