A novel back-contacted solar cell based on a submicron copper indium gallium (di)selenide (CIGS) absorber is proposed and optically investigated. First, charge carrier collection feasibility is studied by band diagram analysis. Then, two back-contacted configurations are suggested and optimized for maximum current production. The results are compared with a reference front/back-contacted CIGS solar cell with a 750-nm-thick absorber. Current density production of 38.84 mA/cm is predicted according to our simulations for a realistic front-side texturing. This shows more than 38% improvement in optical performance compared to the reference cell and only 7.7% deviation from the theoretical Green absorption benchmark.
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http://dx.doi.org/10.1364/OE.27.00A269 | DOI Listing |
ACS Nanosci Au
December 2024
Department of Chemistry, University of Southern California, Los Angeles, California 90089, United States.
Wide band gap AInSe (A = K, Rb, Cs) is an important interlayer material for improving the efficiency of Cu(In,Ga)(S,Se) (CIGS) solar cells. Compared to high-vacuum deposition and solid-state synthesis, a less energy-intensive method is of interest for its fabrication. Herein, we present the rapid, low-temperature colloidal synthesis of AInSe nanocrystals that opens a pathway for convenient solution processing.
View Article and Find Full Text PDFACS Appl Mater Interfaces
November 2024
Department of Electronics and Electrical Engineering, Keio University, 4-1-1 Hiyoshi, Kohoku-ku, Yokohama, Kanagawa 223-8521, Japan.
Wide-bandgap chalcopyrite materials are attractive candidates for a wide variety of energy conversion devices such as the top cell of tandem-type photovoltaic devices and photoelectrochemical water splitting hydrogen evolution devices. Nevertheless, simultaneous realization of high open circuit voltage () and high fill factor (FF) values has been challenging, and thus, the photovoltaic performance has been limited. In this article, high and high FF values of wide-gap chalcopyrite CuGaSe thin-film solar cells are simultaneously demonstrated using an aluminum-induced back-surface field effect.
View Article and Find Full Text PDFMaterials (Basel)
October 2024
College of Physics and Electronic Science, Shanxi Datong University, Datong 037009, China.
In recent years, the efficiency of high-efficiency Cu(In,Ga)Se (CIGS) solar cells has been significantly improved, particularly for narrow-gap types. One of the key reasons for the enhancement of narrow-gap device performance is the formation of the "Spike" structure at the CdS/CIGS heterojunction interface. Wide-gap CIGS solar cells excel in modular production but lag behind in efficiency compared to narrow-gap cells.
View Article and Find Full Text PDFRSC Adv
October 2024
Physics Department, Colleges of Science and General Studies, Alfaisal University P.O. Box 50927 Riyadh 11533 Saudi Arabia
RSC Adv
October 2024
Central R&D LLC Schaumburg IL 60194 USA
It was reported in early 2024 that a single-junction 1.1 eV bandgap copper indium gallium selenide (CIGS) solar cell can achieve actual power conversion efficiency up to 40.70%, open circuit voltage up to 1.
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