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Synthesis of hydrosilanes via Lewis-base-catalysed reduction of alkoxy silanes with NaBH. | LitMetric
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Synthesis of hydrosilanes via Lewis-base-catalysed reduction of alkoxy silanes with NaBH.

Keiya Aoyagi Yu Ohmori Koya Inomata Kazuhiro Matsumoto Shigeru Shimada Kazuhiko Sato Yumiko Nakajima

Chem Commun (Camb)

Department of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8571, Japan and Interdisciplinary Research Center for Catalytic Chemistry, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan.

Published: May 2019

Hydrosilanes were synthesized by reduction of alkoxy silanes with BH in the presence of hexamethylphosphoric triamide (HMPA) as a Lewis-base catalyst. The reaction was also achieved using an inexpensive and easily handled hydride source NaBH, which reacted with EtBr as a sacrificial reagent to form BHin situ.

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 Source
http://dx.doi.org/10.1039/c9cc01961hDOI Listing

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