In the present study, efficient adsorptive removal of fluoride and Direct Blue 53 (DB-53) dye solution on perovskite lanthanum aluminate (PLA) has been investigated. To characterize the prepared PLA with analytical techniques like FTIR, SEM, EDS, PXRD, PHZPC and BET. The influence of adsorbent dose (0.05-0.6) gL, p (2-12), contact time (0-60 min) and initial adsorbate concentration (0-50 mg L) were studied on adsorption process. Mathematical modeling of kinetics and isotherms were computed using equations. The pseudo-second-order kinetic and Halsey isotherm equilibrium model are best fitted with experimentally computed data with R > 0.96. The value of free mean energy E per adsorbate molecule was 1.77 kJmol (fluoride) and 1.86 kJmol (DB-53) with an adsorption capacity 25.103 and 38.03 respectively, hence nature of adsorption suggested as physisorption process. The maximum Langmuir adsorption capacity of PLA was investigated to be 40.8 mgg (fluoride) and 71.4 mgg (DB-53). Present study PLA deficits efficient adsorbent for fluoride and DB-53 dye for ground and industrial wastewater. Further, the effect of in-vitro antimicrobial studies was carried out against six test microorganisms. PLA showed, a maximum antibacterial effect at MIC 63 μg mL for Gram-negative bacteria: Pseudomonas aeruginosa (NCIM 5029) due to the interaction between the positively charged nanoparticle and negatively charged cell wall.
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http://dx.doi.org/10.1016/j.msec.2019.04.013 | DOI Listing |
Inorg Chem
December 2024
Facultad de Farmacia, Departamento de Química y Bioquímica, Urbanización Montepríncipe, Universidad San Pablo-CEU, CEU Universities, Boadilla del Monte, E-28668 Madrid, Spain.
Lanthanum strontium ferrite (LaSrAgFeO = 0; LSFO) and its silver-doped derivative (LaSrAgFeO = 0.05; LASFO) are synthesized using mild conditions by a sol-gel method. Both oxides present a perovskite-like structure with orthorhombic symmetry due to octahedral tilting; thus, the incorporation of silver in the A-site does not significantly modify the perovskite structure.
View Article and Find Full Text PDFAdv Sci (Weinh)
November 2024
Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA.
Inorganic fillers play an important role in improving the ionic conductivity of solid composite electrolytes (SCEs) for Li-ion batteries. Among inorganic fillers, perovskite-type lithium lanthanum titanate (LLTO) stands out for its high bulk Li conductivity on the order of 10 S cm at room temperature. According to a literature survey, the optimal LLTO filler should possess the following characteristics: i) a single-crystal structure to minimize grain boundaries; ii) a small particle size to increase the filler/polymer interface area; iii) a 1D morphology for efficient interface channels; and iv) cubic symmetry to facilitate rapid bulk Li diffusion within the filler.
View Article and Find Full Text PDFACS Nano
November 2024
Department of Analytical and Material Science, BASF SE, Ludwigshafen 67056, Germany.
Analyst
November 2024
Institute of Ecology and Genetics of Microorganisms, Urals Branch of RAS, Perm, Russia.
LaNiO perovskite nanoparticles, especially nanospheres (LNNS), show great promise in biomedical assays due to their peroxidase-like catalytic properties. However, LNNS-based diagnostic reagents have not been tested in nanozyme enzyme-linked immunosorbent assay (NLISA) or other enzyme-linked immunosorbent assays, and there is limited data on their synthesis. To fill this gap, it is necessary to develop a method for creating LNNS conjugates with monoclonal antibodies and to investigate the reproducibility, scalability, and applicability of these diagnostic reagents in NLISA.
View Article and Find Full Text PDFChemSusChem
October 2024
Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST), 291 Daehak-Ro, Daejeon, 34141, Republic of Korea.
The properties of an oxygen carrier, such as crystalline structure, textural properties, and surface chemical species, significantly influence the redox performance in thermochemical redox applications. This study presents the synthesis of various lanthanum orthoferrite (LaFeO) perovskites by adjusting Pechini synthesis parameters, including chelating agent ratio, calcination temperature, and solution pH. A larger surface area emerged as a dominant factor contributing to improved redox performance.
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