This work presents a non-invasive, reusable and submersible permittivity sensor that uses a microwave technique for the dielectric characterization of liquid materials. The proposed device consists of a compact split ring resonator excited by two integrated monopole antennas. The sensing principle is based on the notch introduced by the resonators in the transmission coefficient, which is affected due to the introduction of the sensor in a new liquid material. Then, a frequency shift of the notch and the Q-factor of the proposed sensor are related with the changes in the surrounding medium. By means of a particular experimental procedure, commercial liquids are employed to obtain the calibration curve. Thus, a mathematical equation is obtained to extract the dielectric permittivity of liquid materials with unknown dielectric properties. A good match between simulated and experimental results is obtained, as well as a high Q-factor, compact size, good sensitivity and high repeatability for use in sensing applications. Sensors like the one here presented could lead to promising solutions for characterizing materials, particularly in determining material properties and quality in the food industry, bio-sensing and other applications.
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http://dx.doi.org/10.3390/s19081936 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016, India.
Hydrogen production via water-splitting or ammonia electrolysis using transition metal-based electrodes is one of the most cost-effective approaches. Herein, ca. 1-4% of Pt atoms are stuffed into a wolframite-type NiWO lattice to improve the electrocatalytic efficiency.
View Article and Find Full Text PDFMolecules
January 2025
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninsky Prosp. 31, 119991 Moscow, Russia.
The interaction of sodium phytate hydrate CHOP·xNa·yHO (phytNa) with Cu(OAc)·HO and 1,10-phenanthroline (phen) led to the anionic tetranuclear complex [Cu(HO)(phen)(phyt)]·2Na·2NH·32HO (), the structure of the latter was determined by X-ray diffraction analysis. The phytate is completely deprotonated; six phosphate fragments (with atoms P1-P6) are characterized by different spatial arrangements relative to the cyclohexane ring (1a5e conformation), which determines two different types of coordination to the complexing agents-P1 and P3, P4, and P6 have monodentate, while P2 and P5 are bidentately bound to Cu cations. The molecular structure of the anion complex is stabilized by a set of strong intramolecular hydrogen bonds involving coordinated water molecules.
View Article and Find Full Text PDFNanomaterials (Basel)
January 2025
School of Physics and Optoelectronics, South China University of Technology, Guangzhou 510640, China.
Artificial microstructures, especially metamaterials, have garnered increasing attention in numerous applications due to their rich and distinctive properties. Starting from the principle of multi-beam interference, we have theoretically devised a beam configuration consisting of six symmetrically distributed coherent beams to generate two-dimensional microstructures with diverse shapes of unitcells under different polarization combinations. In particular, a split-ring metamaterial template is achieved with two adjacent circularly and four linearly polarized beams with such single-step holographic interferometry.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Electrical, Electronic and Systems Engineering, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia (UKM), 43600, Bangi, Selangor, Malaysia.
This research presents the design and analysis of a compact metamaterial (MTM)-based star-shaped split-ring resonator (SRR) enclosed in a square, constructed on a cost-effective substrate for liquid chemical sensing applications. The designed structure has dimensions of 10 × 10 mm and is optimized for detecting adulteration in edible oils. When the sample holder is filled with different percentages of oil samples, the resonance frequency of the MTM-based SRR sensor shift significantly.
View Article and Find Full Text PDFACS Sens
January 2025
State Key Laboratory of Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130012, P. R. China.
Chemiresistive sensors are currently the most popular gas sensors, and metal semiconductor oxides are often used as sensitive materials (SMs). However, their high operating temperature means that more energy is required to maintain normal operation of the SM, resulting in an increase in power consumption of the entire sensing system. In order to solve this problem, a microwave gas sensor embedded with multilayer TiCT MXene and split ring resonator (SRR) for nitrogen dioxide (NO) detection was reported in this work.
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