FeSnO Composites as Anode Materials for Lithium-Ion Storage.

J Nanosci Nanotechnol

Department of Chemical and Biological Engineering, Gachon University, Seongnam-si, Gyeonggi-do, 13120, Republic of Korea.

Published: October 2019

AI Article Synopsis

  • A novel composite material, FeSnO, was created by combining tin oxide and iron oxide through a galvanic replacement reaction.
  • The study utilized techniques like X-ray diffraction and electron microscopy to analyze the composite's morphology, structure, and composition.
  • When tested as an anode for lithium-ion batteries, the FeSnO composite with a poly(acrylic acid) binder outperformed the one with polyvinylidene fluoride, highlighting the importance of binder choice for better electrochemical performance.

Article Abstract

A novel composite, FeSnO, consisting of tin oxide and iron oxide was developed via a galvanic replacement reaction. The morphology, crystalline structure, and composition of the FeSnO composite were investigated by employing X-ray diffraction, energy dispersive X-ray spectroscopy, and transmission electron microscopy. When evaluated as an anode material using different binders, namely, polyvinylidene fluoride (PVDF) and poly(acrylic acid) (PAA), the composite blended with the PAA binder displayed a high coulombic efficiency and excellent cycling stability compared to the composite mixed with the PVDF binder. The excellent electrochemical performance could be attributed to the different interactions between the current collector and the binders, as well as the volume accommodation during cycling. Therefore, the results indicated that the application of an appropriate binder could lead to a significant improvement in the electrochemical performance of FeSnO composite anodes for lithium-ion batteries.

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Source
http://dx.doi.org/10.1166/jnn.2019.17088DOI Listing

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