Two-dimensional arrays of hollow nanotubes made of TiO 2 are a promising platform for sensing, spectroscopy and light harvesting applications. Their straightforward fabrication via electrochemical anodization, growing nanotube pillars of finite length from a Ti foil, allows precise tailoring of geometry and, thus, material properties. We theoretically investigate these photonic crystal structures with respect to reduction of front surface reflection, achievable field enhancement, and photonic bands. Employing the Rigorous Coupled Wave Analysis (RCWA), we study the optical response of photonic crystals made of thin-walled nanotubes relative to their bare Ti foil substrate, including under additional charge carrier doping which might occur during the growth process.
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http://dx.doi.org/10.3390/ma12081332 | DOI Listing |
Materials (Basel)
November 2024
Department of Electrical Engineering, National Cheng Kung University, Tainan 70101, Taiwan.
Perovskite solar cells are among the most promising renewable energy devices, and enhancing their stability is crucial for commercialization. This research presents the use of L-Ergothioneine (L-EGT) as a passivation material in perovskite solar cells, strategically placed between the electron transport layer and the perovskite absorber layer to mitigate defect states at the heterojunction interface. Surface analysis reveals that introducing L-EGT passivation material significantly improves the quality of the perovskite film.
View Article and Find Full Text PDFACS Nano
December 2024
Energy Conversion and Storage Systems Center, National Renewable Energy Laboratory, Golden, Colorado 80401, United States.
Photocatalytic water splitting is a promising route to low-cost, green H. However, this approach is currently limited in its solar-to-hydrogen conversion efficiency. One major source of efficiency loss is attributed to the high rates of undesired side and back reactions, which are exacerbated by the proximity of neighboring oxidation and reduction sites.
View Article and Find Full Text PDFJ Colloid Interface Sci
March 2025
School of Environmental Science and Engineering, Yancheng Institute of Technology, Yancheng 224051, PR China. Electronic address:
Perfluorinated compounds (PFCs), recognized as persistent organic pollutants, resist degradation in the environment due to the high bond energy of the C-F. Increasing carrier density via adopting electrostatic self-assembly strategy has been shown to effectively cleave C-F bonds. In this work, a unique S-scheme structure was fabricated by combining oppositely charged semiconductors, TiO and ReS, through electrostatic self-assembly.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
November 2024
Department of Chemistry, Savitribai Phule Pune University, Ganeshkhind, Pune, 411007, India.
Talanta
January 2025
College of Chemical and Biological Engineering, Shandong University of Science and Technology, Qingdao, 266590, PR China. Electronic address:
Although porphyrin modification can improve the peroxidase-like activity of some inorganic nanozymes, it is hardly studied that metal porphyrin self-assembled nanoaggregates as sacrificial templates to turn on the peroxidase-like activity of inorganic nanozymes under light illumination. In this work, cobalt (II) 5,10,15,20-Tetrakis (4-carboxylpheyl)porphyrin (CoTCPP) self-assembled nanoaggregates are firstly used as soft templates to prepare TiO-based nanozymes with the enhanced peroxidase-like activity. Interestingly, CoTCPP nanoaggregates can be changed into Co oxide nanoparticles dispersed into the nanosphere composites.
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