Ring Statistics in 2D Silica: Effective Temperatures in Equilibrium.

Phys Rev Lett

Institute für Physikalische Chemie, Westfälische-Wilhelms-Universität Münster, Corrensstraße 28/30, 48149 Münster, Germany.

Published: January 2019

The thermodynamic properties of subsystems in strong interaction with the neighborhood can largely differ from the standard behavior. Here we study the thermodynamic properties of rings and triplets in equilibrated disordered 2D silica. Their statistics follows a Boltzmann behavior, albeit with a strongly reduced temperature. This effective temperature strongly depends on the length scale of the chosen subsystem. From a systematic analysis of the 1D Ising model and an analytically solvable model, we suggest that these observations reflect the presence of strong local positive energy correlations.

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http://dx.doi.org/10.1103/PhysRevLett.122.016104DOI Listing

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