Improved Aging Stability of Ethylene-Norbornene Composites Filled with Lawsone-Based Hybrid Pigment.

In this study, we produced a new organic-inorganic hybrid pigment based on a natural chromophore. Lawsone was selected as the active organic compound and incorporated into aluminum-magnesium hydroxycarbonate (LH). The hydroxynaphthoquinone derivative lawsone (.) is a naturally occurring dye, which is commonly used as a colorant because of its nontoxicity and biological functions. The structure and stability of the hybrid colorant were investigated using 27-Al solid-state nuclear magnetic resonance (NMR) spectroscopy, X-ray diffraction (XRD), secondary ion mass spectrometry (TOF-SIMS), thermogravimetric analysis (TGA), scanning electron microscopy (SEM) and UV-Vis spectroscopy. TOF-SIMS and Al NMR spectroscopy revealed interactions between the dye molecules and metal ions present in the LH host, confirming successful formation of an LH-based hybrid (LH/lawsone). In the next part of the study, we examined the effect of the hybrid pigment on the mechanical and thermal properties of ethylene-norbornene (EN) materials, as well as the aging resistance of the colored composites to irradiation across the full solar spectrum. Dynamic mechanical analysis (DMA) and the results of tensile break tests revealed that the EN+LH/lawsone composite had significantly better resistance to solar irradiation in comparison to EN and EN with an unmodified carrier.