AI Article Synopsis

Article Abstract

In this study a novel technique, micro-focus time-resolved laser-induced luminescence spectroscopy (µTRLFS) is presented to investigate heterogeneous systems like granite (mainly consisting of quartz, feldspar, and mica), regarding their sorption behavior. µTRLFS is a spatially-resolved upgrade of conventional TRLFS, which allows point-by-point analysis of single minerals by reducing the beam size of the analytic laser beam to below the size of mineral grains. This provides visualization of sorption capacity as well as speciation of a luminescent probe, here Eu. A thin-section of granitic rock from Eibenstock, Saxony, Germany was analyzed regarding its mineralogy with microprobe X-ray fluorescence (µXRF) and electron probe microanalysis (EPMA). Afterwards, it was reacted with 5.0 × 10 mol/L Eu at pH 8.0 and uptake was quantified by autoradiography. Finally, the µTRLFS studies were conducted. The results clearly show that the materials interact differently with Eu, and often even on one mineral grain different speciations can be found. Alkali-feldspar shows very high uptake, with an inhomogeneous distribution, and intermediate sorption strength. On quartz uptake is almost 10-fold lower, while the complexation strength is higher than on feldspar. This may be indicative of adsorption only at surface defect sites, in accordance with low hydration of the observed species.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6472502PMC
http://dx.doi.org/10.1038/s41598-019-42664-2DOI Listing

Publication Analysis

Top Keywords

beam size
8
sorption
4
sorption euiii
4
euiii eibenstock
4
eibenstock granite
4
granite studied
4
µtrlfs
4
studied µtrlfs
4
µtrlfs novel
4
novel spatially-resolved
4

Similar Publications

Aim: This study aimed to evaluate the prevalence, location and diameters of Posterior superior alveolar artery (PSAA) and Infraorbital foramen (IOF) to find out whether there is any relationship between PSAA and IOF, and to predict their location relative to each other in surgical procedures by using cone beam computed tomography (CBCT).

Material And Method: Bilateral maxillary sinuses were analysed retrospectively in 170 patients with no missing teeth in the maxillary posterior region. The largest locations of PSAA and IOF in the maxillary sinus were determined and their size, shape, location in relation to the teeth and distances from anatomical points were evaluated.

View Article and Find Full Text PDF

Objectives: This study aimed to develop an automated method for generating clearer, well-aligned panoramic views by creating an optimized three-dimensional (3D) reconstruction zone centered on the teeth. The approach focused on achieving high contrast and clarity in key dental features, including tooth roots, morphology, and periapical lesions, by applying a 3D U-Net deep learning model to generate an arch surface and align the panoramic view.

Methods: This retrospective study analyzed anonymized cone-beam CT (CBCT) scans from 312 patients (mean age 40 years; range 10-78; 41.

View Article and Find Full Text PDF

The field of chiral nanoparticles is rapidly expanding, yet measuring the chirality of single nano-objects remains a challenging endeavor. Here, we report a technique to detect chiro-optical effects in single plasmonic nanoparticles by means of phase-sensitive polarization-resolved four-wave mixing interferometric microscopy. Beyond conventional circular dichroism, the method is sensitive to the particle polarizability, in amplitude and phase.

View Article and Find Full Text PDF

Purpose: Cochlear implants (CI) are the most successful bioprosthesis in medicine probably due to the tonotopic anatomy of the auditory pathway and of course the brain plasticity. Correct placement of the CI arrays, respecting the inner ear anatomy are therefore important. The ideal trajectory to insert a cochlear implant array is defined by an entrance through the round window membrane and continues as long as possible parallel to the basal turn of the cochlea.

View Article and Find Full Text PDF

Objective: To assess tumour factors that reduce primary technical efficacy (PTE) from CT-guided renal cryoablation.

Methods: Patients were taken from the EuRECA registry between December 2014 and November 2020. To focus on tumour factors rather than individual technique, this study was limited to cases using CT and excluded procedures using cone beam, US, MRI, or laparoscopy.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!