In order to fabricate high performance fiber pseudocapacitors, the trade-off between high mass loading and high utilization efficiency of pseudocapacitive materials should be carefully addressed. Here, a solution that is to construct a carbon-based versatile scaffold is reported for loading pseudocapacitive materials on carbonaceous fibers. The scaffold can be easily built by conformally coating commercial pen ink on the fibers without any destruction to the fiber skeleton. Due to the high electrical conductivity and abundant macropore structure, it can provide sufficient loading room and a high ion/electron conductive network for pseudocapacitive materials. Therefore, their loading mass and utilization efficiency can be increased simultaneously, and thus the as-designed fibrous electrode displays a high areal capacitance of 649 mF cm (or 122 mF cm based on length), which is higher than most of the reported fiber pseudocapacitors. The simple and low-cost strategy opens up a new way to prepare high performance portable/wearable energy storage devices.
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http://dx.doi.org/10.1002/smll.201900721 | DOI Listing |
Sci Adv
June 2023
Materials Science Engineering Program, University of California San Diego, La Jolla, CA 92093, USA.
Structural supercapacitors hold promise to expand the energy capacity of a system by integrating load-bearing and energy-storage functions in a multifunctional structure, resulting in weight savings and safety improvements. Here, we develop strategies based on interfacial engineering to advance multifunctional efficiency. The structural electrodes were reinforced by coating carbon-fiber weaves with a uniquely stable conjugated redox polymer and reduced graphene oxide that raised pseudocapacitive capacitance and tensile strength.
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April 2023
Silicon Hall: Micro/Nano Manufacturing Facility, Faculty of Engineering and Applied Science, Ontario Tech University, 2000 Simcoe St N, Oshawa, ON, L1G 0C5, Canada.
Developing a cost-effective pseudocapacitor electrode manufacturing process incorporating binder-free, green synthesis methods and single-step fabrication is crucial in advancing supercapacitor research. This study aims to address this pressing issue and contribute to the ongoing efforts in the field by introducing ULPING (Ultra-short Laser Pulse for In-situ Nanostructure Generation) technique for effective design. Laser irradiation was conducted in ambient conditions to form a CuO/NiO hybrid structure providing a synergistic contribution to the electrical behavior of the electrode.
View Article and Find Full Text PDFPolymers (Basel)
November 2022
"Petru Poni" Institute of Macromolecular Chemistry, 41A Grigore Ghica Voda Alley, 700487 Iasi, Romania.
In this work, pure TiO and Cu (0.5, 1, 2%)-doped TiO composites prepared by electrospinning technique followed by calcination at 900 °C, and having high pseudocapacitive and dielectric characteristics were reported. These nanocomposites were characterized by scanning electron microscopy, X-ray diffraction, and dynamic water sorption vapor measurements.
View Article and Find Full Text PDFFront Chem
May 2022
School of Engineering, Australian National University, Canberra, ACT, Australia.
Durable and safe energy storage is required for the next generation of miniature bioelectronic devices, in which aqueous electrolytes are preferred due to the advantages in safety, low cost, and high conductivity. While rechargeable aqueous batteries are among the primary choices with relatively low power requirements, their lifetime is generally limited to a few thousand charging/discharging cycles as the electrode material can degrade due to electrochemical reactions. Electrical double layer capacitors (EDLCs) possess increased cycling stability and power density, although with as-yet lower energy density, due to quick electrical adsorption and desorption of ions without involving chemical reactions.
View Article and Find Full Text PDFInt J Biol Macromol
December 2021
College of Life Sciences, Qingdao Agricultural University, Qingdao 266109, China. Electronic address:
In this work, lignin-based carbon nanofibers (LCNFs) were for the first time served as substrate for in-situ electrodeposition of polyaniline (PANI) and tested as pseudocapacitor. Two LCNFs with different lignin ratios were designed to distinguish their morphology and structural properties. Next, PANI deposition mechanisms on both LCNFs were investigated and the electrochemical performance of the resulting LCNF/PANIs were evaluated.
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