pH-Dependent structure of water-exposed surfaces of CdSe quantum dots.

Chem Commun (Camb)

Department of Chemistry, Northwestern University, 2145 Sheridan Rd., Evanston, IL 60208-3113, USA.

Published: May 2019

Increasing negative charge density at the surfaces of CdSe quantum dots (QDs) effects a bathochromic shift of their ground state optical spectra with increasing pH due to electrostatic and chemical modifications at the QD surface. These modifications are enabled by weakly-bound ligands that expose the surface to the aqueous environment.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6556383PMC
http://dx.doi.org/10.1039/c9cc01339cDOI Listing

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