In cross-flow membrane filtration, fouling results from material deposit which clogs the membrane inner surface. This hinders filtration, which experiences the so-called limiting flux. Among the models proposed by the literature, we retain a simple one: a steady-state reversible fouling is modelled with the use of a single additional parameter, i.e., N d , the ratio of the critical concentration for deposition to the feed concentration at inlet. To focus on fouling, viscous pressure drop and osmotic (counter-)pressure have been chosen low. It results in a minimal model of fouling. Solved thoroughly with the numerical means appropriate to enforce the nonlinear coupling between permeation and concentration polarization, the model delivers novel information. It first shows that permeation is utterly governed by solute transfer, the relevant non-dimensional quantities being hence limited to N d and P e i n , the transverse Péclet number. Furthermore, when the role played by N d and moderate P e i n (say P e i n < 40 ) is investigated, all results can be interpreted with the use of a single non-dimensional parameter, F l , the so-called fouling number, which simply reads F l ≡ P e i n N d - 1 . Now rendered possible, the overall fit of the numerical data allows us to put forward analytical final expressions, which involve all the physical parameters and allow us to retrieve the experimental trends.
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http://dx.doi.org/10.3390/membranes9040048 | DOI Listing |
Anal Chem
January 2025
College of Chemistry, Beijing Normal University, Beijing 100875, China.
5-Hydroxyindoleacetic acid (5-HIAA), a vital metabolite of serotonin (5-HT), is crucial for understanding metabolic pathways and is implicated in various mental disorders. In situ monitoring of 5-HIAA is challenging due to the lack of affinity ligands and issues with electrochemical fouling. We present an advanced sensing approach that integrates customizable molecular imprinting polymer (MIP) with self-driven galvanic redox potentiometry (GRP) for precise, real-time in vivo monitoring of 5-HIAA.
View Article and Find Full Text PDFMembranes (Basel)
January 2025
Ralph E. Martin Department of Chemical Engineering, University of Arkansas, Fayetteville, AR 72701, USA.
Virus filtration is used to ensure the high level of virus clearance required in the manufacture of biopharmaceutical products such as monoclonal antibodies. Flux decline during virus filtration can occur due to the formation of reversible aggregates consisting of self-assembled monomeric monoclonal antibody molecules, particularly at high antibody concentrations. While size exclusion chromatography is generally unable to detect these reversible aggregates, dynamic light scattering may be used to determine their presence.
View Article and Find Full Text PDFMembranes (Basel)
January 2025
Industrial Systems Engineering, Produced Water Treatment Laboratory, Faculty of Engineering and Applied Science, University of Regina, Regina, SK S4S 0A2, Canada.
Access to clean and reliable water has become a critical concern due to the global water crisis. High sulfate levels in drinking water raise health concerns for humans and animals and can cause serious corrosion in industrial systems. Sulfated waters represent a major challenge on the Canadian prairies, leading to many cattle deaths.
View Article and Find Full Text PDFJ Environ Manage
January 2025
Chemical Engineering Department, Faculty of Industrial Technology, Institut Teknologi Bandung, Jl. Ganesha 10, Bandung, 40132, Indonesia; Research Center for Biosciences and Biotechnology, Institut Teknologi Bandung, Jl. Ganesha 10, Bandung, 40132, Indonesia.
This article reviews the role of membrane systems in treating palm oil mill effluent (POME), a waste generated by the palm industry. The review focuses on various membrane systems such as microfiltration (MF), ultrafiltration (UF), nanofiltration (NF), and reverse osmosis (RO), highlighting their effectiveness in removing pollutants and recovering water. Special attention is given to hybrid systems integrating membrane bioreactors (MBRs) and other advanced processes to enhance fouling control, improve water quality, and promote sustainability.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Key Laboratory of Pulp and Paper Science and Technology of Shandong Province, Ministry of Education, State Key Laboratory of Biobased Material and Green Papermaking, Qilu University of Technology, Shandong Academy of Sciences, Jinan 250353, Shandong, China.
The high salt content and color are regarded as a major challenge to the reuse of industrial wastewater. In the present study, the application of cellulose acetate reverse osmosis (RO) membrane in combination with microfiltration (MF), ultrafiltration (UF), or nanofiltration (NF) process was investigated in the purification of biological and Fenton treated pulp and paper wastewater. In the first step, the effect of pH and inlet pressures on the membrane fouling was investigated.
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