Tunneling spectroscopy of one-dimensional interacting wires can be profoundly sensitive to the boundary conditions of the wire. Here, we analyze the tunneling spectroscopy of a wire coupled to capacitive metallic leads. Strikingly, with increasing many-body interactions in the wire, the impact of the boundary noise becomes more prominent. This interplay allows for a smooth crossover from standard 1D tunneling signatures into a regime where the tunneling is dominated by the fluctuations at the leads. This regime is characterized by an elevated zero-bias tunneling alongside a universal power-law decay at high energies. Furthermore, local tunneling measurements in this regime show a unique spatial dependence that marks the formation of plasmonic standing waves in the wire. Our result offers a tunable method by which to control the boundary effects and measure the interaction strength (Luttinger parameter) within the wire.
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http://dx.doi.org/10.1103/PhysRevLett.122.126802 | DOI Listing |
Sci Rep
December 2024
Geotechnical Institute, TU Bergakademie Freiberg, Freiberg, Germany.
The development of new urban areas necessitates building on increasingly scarce land, often overlaid on weak soil layers. Furthermore, climate change has exacerbated the extent of global arid lands, making it imperative to find sustainable soil stabilization and erosion mitigation methods. Thus, scientists have strived to find a plant-based biopolymer that favors several agricultural waste sources and provides high strength and durability for sustainable soil stabilization.
View Article and Find Full Text PDFJ Inorg Biochem
December 2024
Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires C1428EGA, Argentina; Instituto de Química Física de Los Materiales, Medio Ambiente y Energía (INQUIMAE), CONICET-Universidad de Buenos Aires, Buenos Aires C1428EGA, Argentina. Electronic address:
Here, we show that the replacement of the distal residues Asp and/or Arg of the DyP peroxidases from Bacillus subtilis and Pseudomonas putida results in functional enzymes, albeit with spectroscopically perturbed active sites. All the enzymes can be activated either by the addition of exogenous HO or by in situ electrochemical generation of the reactive oxygen species (ROS) OH, O and HO. The latter method leads to broader and upshifted pH-activity profiles.
View Article and Find Full Text PDFACS Nano
December 2024
Center for Advanced Quantum Studies, School of Physics and Astronomy, Beijing Normal University, Beijing 100875, China.
Introducing quantum confinement has shown promise to enable control of charge carriers. Although recent advances make it possible to realize confinement from semiclassical regime to quantum regime, achieving control of electronic potentials in individual nanoscale quantum dots (QDs) has remained challenging. Here, we demonstrate the ability to tune quantum confined states in individual nanoscale graphene QDs, which are realized by inserting nanoscale monolayer WSe islands in graphene/WSe heterostructures via interfacial engineering.
View Article and Find Full Text PDFRev Sci Instrum
December 2024
2nd Institute of Physics B and JARA-FIT, RWTH Aachen University, 52074 Aachen, Germany.
Low-temperature scanning tunneling spectroscopy is a key method to probe electronic and magnetic properties down to the atomic scale, but suffers from extreme vibrational sensitivity. This makes it challenging to employ closed-cycle cooling with its required pulse-type vibrational excitations, albeit this is mandatory to avoid helium losses for counteracting the continuously raising helium prices. Here, we describe a compact ultra-high vacuum scanning tunneling microscope (STM) system with an integrated primary pulse tube cooler (PTC) for closed-cycle operation.
View Article and Find Full Text PDFJ Phys Chem Lett
December 2024
Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123, P. R. China.
Alkali element doping has significant physical implications for two-dimensional materials, primarily by tuning the electronic structure and carrier concentration. It can enhance interface electronic interactions, providing opportunities for effective charge transfer at metal-organic interfaces. In this work, we investigated the effects of gradually increasing the level of K doping on the lattice structure and electronic properties of an organometallic coordinated Kagome lattice on a Ag(111) surface.
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