Surface modification becomes an effective tool for improvement of both flux and selectivity of membrane by reducing the adsorption of the components of the fluid used onto its surface. A successful green modification of poly(ethersulfone) (PES) membranes using ortho-aminophenol (2-AP) modifier and laccase enzyme biocatalyst under very flexible conditions is presented in this paper. The modified PES membranes were evaluated using many techniques including total color change, pure water flux, and protein repellence that were related to the gravimetric grafting yield. In addition, static water contact angle on laminated PES layers were determined. Blank and modified commercial membranes (surface and cross-section) and laminated PES layers (surface) were imaged by scanning electron microscope (SEM) and scanning probe microscope (SPM) to illustrate the formed modifying poly(2-aminophenol) layer(s). This green modification resulted in an improvement of both membrane flux and protein repellence, up to 15.4% and 81.27%, respectively, relative to the blank membrane.
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http://dx.doi.org/10.3390/polym8080306 | DOI Listing |
J Am Chem Soc
January 2025
School of Rare Earths, University of Science and Technology of China, Hefei 230026, China.
Achieving ultrahigh permeance and superoleophobicity is crucial for membrane application. Here, we demonstrated that a poly(ionic liquid)/PES hydrogel membrane can achieve dual goals. The high polarity of the ionic liquids induces the water molecules on the membrane surface to be arranged more ordered, as verified by molecular dynamics (MD) simulation and advanced femtosecond sum frequency generation (SFG) vibrational spectroscopy.
View Article and Find Full Text PDFEnviron Sci Technol
January 2025
Department of Civil and Environmental Engineering, The Hong Kong Polytechnic University, Kowloon, Hong Kong 999077, China.
Polyelectrolyte multilayer (PEM) membranes, with advantageous features of versatile chemistry and structures, are driving the development of advanced nanofiltration (NF) membranes with exceptional performance. While developing a printing method holds great promise for the eventual mass production of these membranes, reports on the printing method and the underlying mechanisms of membrane formation are currently scarce. Herein, we develop an aerosol-assisted printing (AAP) system for fabricating PEM NF membranes with highly tunable separation characteristics.
View Article and Find Full Text PDFEng Life Sci
January 2025
Lab Essentials Applications Development Sartorius Göttingen Germany.
The demand for lentiviral vectors (LVs) as tools for ex vivo gene therapies is ever-increasing. Despite their promising applications, challenges in LV production remain largely due to the fragile envelope, which challenges the maintenance of vector stability. Thus, downstream processing optimization to enhance efficiency, yield, and product quality is necessary.
View Article and Find Full Text PDFJ Lipid Res
January 2025
Institute of Pharmaceutical Sciences, Department of Pharmaceutical Chemistry, University of Graz, Graz, Austria; Field of Excellence BioHealth - University of Graz, Graz, Austria. Electronic address:
Phospholipids containing oxidized esterified PUFA residues (OxPLs) are increasingly recognized for multiple biological activities and causative involvement in disease pathogenesis. Pharmacokinetics of these compounds in blood plasma is essentially not studied. Human plasma contains both genuine phospholipases A (PAF-AH (also called Lp-PLA) and sPLA) and multifunctional enzymes capable of removing sn-2 residues in native and oxidized PLs (LCAT, PRDX6).
View Article and Find Full Text PDFSci Rep
January 2025
College of Resource and Civil Engineering, Northeast University, Shenyang, China.
This study presents the fabrication and characterization of mixed matrix membranes (MMMs) incorporating green-synthesized silver nanoparticles (AgNPs) using Hibiscus Rosa sinensis extract within a polyethersulfone (PES) matrix for nanofiltration (NF) application. The membranes were evaluated for their pure water permeability, salt rejection, dye removal, and antifouling performance. Results showed that the membrane with 0.
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