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Selective biocatalytic hydroxylation of unactivated methylene C-H bonds in cyclic alkyl substrates. | LitMetric
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Selective biocatalytic hydroxylation of unactivated methylene C-H bonds in cyclic alkyl substrates.

Md Raihan Sarkar Samrat Dasgupta Simon M Pyke Stephen G Bell

Chem Commun (Camb)

Department of Chemistry, University of Adelaide, Adelaide, SA 5005, Australia.

Published: April 2019

The cytochrome P450 monooxygenase CYP101B1 from Novosphingobium aromaticivorans selectively hydroxylated methylene C-H bonds in cycloalkyl rings. Cycloketones and cycloalkyl esters containing C6, C8, C10 and C12 rings were oxidised with high selectively on the opposite side of the ring to the carbonyl substituent. Cyclodecanone was oxidised to oxabicycloundecanol derivatives in equilibrium with the hydroxycyclodecanones.

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 Source
http://dx.doi.org/10.1039/c9cc02060hDOI Listing

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