High-Performance TiO₂ Nanotubes/Poly(aryl ether sulfone) Hybrid Self-Cleaning Anti-Fouling Ultrafiltration Membranes.

A series of novel self-cleaning hybrid photocatalytic ultrafiltration (UF) membranes were fabricated to separate polyacrylamide, which is widely used as a commercial flocculant. To maximize the self-cleaning and anti-fouling properties of hybrid membranes, high surface area TiO₂ nanotubes (TNTs) with excellent photocatalytic activity were homogeneously introduced into a poly(aryl ether sulfone) matrix by chemical bonds. The chemical structure, micromorphology, hydrophilicity, separation efficiency, fouling behavior, and self-cleaning property of the prepared hybrid membranes were well characterized and evaluated. For the optimal sample, the flux recovery ratio increased from ~40% to ~80% after simulated sunlight irradiation for 20 min, which was attributable to the homogeneous dispersion and efficient photocatalytic degradation ability of TNTs. Furthermore, the intelligent fabrication strategy enhanced the anti-aging ability of the hybrid membranes via the use of a fluorine-containing poly matrix. This work provided new insight into the fabrication of high-performance self-cleaning inorganic/organic hybrid membranes.