Insights into the activation of ozonation by hydroxylamine: Influential factors, degradation mechanism and reaction kinetics.

J Hazard Mater

School of Environmental Engineering, Wuhan Textile University, No.1 Sunshine Avenue, Wuhan, 430200, China; Engineering Research Center for Clean Production of Textile Dyeing and Printing, Ministry of Education, No.1 Sunshine Avenue, Wuhan, 430200, China. Electronic address:

Published: July 2019

The decontamination of prometon (PMT) by ozone/hydroxylamine hydrochloride (O/HAC) was systematically investigated in this study with focus on the degradation mechanism and kinetics. Experimental results revealed that there was an enhancement of PMT degradation efficiency by 42.1% and the pseudo-first-order rate constant by more than 5.7 times in O/HAC process under low HAC dosage (5 mg L) after 3 min in comparison with O alone. The second-order rate constant of PMT with hydroxyl radical (OH) was determined to be (1.84 ± 0.1) × 10 M s and 7.80 × 10 M s via competition kinetics and OH steady-state hypothesis, respectively. The PMT removal in O/HAC process was highly pH-dependent and the optimum degradation performance was achieved under pH 5.0. In addition, OH and singlet oxygen were identified as the primary reactive oxygen radicals in O/HAC process. Meanwhile, eleven transformation products of PMT were identified and possible degradation mechanisms were proposed. Moreover, a kinetic model based on chemical kinetics and steady-state hypothesis was developed and modified to predict the PMT abatement in O/HAC process. The results demonstrated that the O/HAC process provided a promising alternative for refractory organic pollutants decontamination in water treatment.

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http://dx.doi.org/10.1016/j.jhazmat.2019.03.121DOI Listing

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