Periphery Design of Macrocyclic Materials for Organic Light-Emitting Devices with a Blue Phosphorescent Emitter.

Org Lett

Department of Chemistry, The University of Tokyo, and JST, ERATO, Isobe Degenerate π-Integration Project, Hongo 7-3-1, Bunkyo-ku, Tokyo 113-0033 , Japan.

Published: April 2019

Cyclo- meta-phenylenes were modified with trifluoromethyl groups at their periphery to create host materials suitable for use in blue phosphorescent organic light-emitting devices. The periphery design resulted in molecules with high triplet-state energies, which were required to support the blue emission from Ir phosphors. As a result, an external quantum efficiency of 9.9% was achieved. The most successful host, a pentameric congener, preferred CF-π/CH-π interactions in its crystalline packings, which could be beneficial for the host performance.

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Source
http://dx.doi.org/10.1021/acs.orglett.9b00717DOI Listing

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