Ethyl + O in Helium Nanodroplets: Infrared Spectroscopy of the Ethylperoxy Radical.

Helium-solvated ethylperoxy radicals (CHCHOO) are formed via the in situ reaction between A' ethyl radical and Σ dioxygen. The reactants are captured sequentially through the droplet pick-up technique. Helium droplets are doped with ethyl radical via pyrolysis of di- tert-amyl peroxide or n-propylnitrite in an effusive, low-pressure source. An infrared spectrum of ethylperoxy, in the CH stretching region, is recorded with species-selective droplet beam depletion spectroscopy. Spectral assignments are made via comparisons to second-order vibrational perturbation theory with resonances (VPT2 + K) based on coupled-cluster full quartic force fields. Cubic and quartic force constants, evaluated using a small basis set, are transformed into the normal coordinate system of the higher level quadratic force constants. This transformation procedure eliminates the mismatch between normal modes, which is a source of error whenever normal coordinate force constants from different levels of theory are combined. The spectrum shows signatures of both the C gauche and C trans rotamers in an approximate 2:1 ratio; this is despite the prediction that the gauche rotamer lies 44 cm lower on the zero-Kelvin enthalpic potential surface for torsional interconversion. Helium droplets are 0.4 K at equilibrium; therefore, in situ ethylperoxy production is highly nonthermal.