Treatment of coking wastewater is a great challenge due to their instinct characteristics of high concentration, complex composition and biological toxicity. In this work, a novel integrated system comprising three-dimensional electrochemical reactors (3DERs) and three-dimensional biofilm electrode reactors (3DBERs) in series is developed for coking wastewater treatment. Results indicate that 79.63% of COD as well as 76.30% of total nitrogen could be removed at the low energy consumption of 15.6 kWh/m. 3DERs mainly contribute to COD and nitrogen removal through electrochemical oxidation/reduction, while 3DBERs are responsible for nitrification process by enriched functional microbes. After treating by the integrated system, only long-chain alkanes are left in the wastewater and the toxicity of effluent is significantly reduced. This integrated 3DERs-3DBERs system exhibits capability of simultaneously eliminating carbonaceous and nitrogenous contaminants in coking wastewater, and greatly saves the energy with synergy of electricity and biofilm.
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http://dx.doi.org/10.1016/j.biortech.2019.03.123 | DOI Listing |
Nanoscale
January 2025
College of Chemical Engineering, State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China.
Interfacial solar vapor generation (ISVG) accompanied by photocatalytic degradation holds immense potential to mitigate water scarcity and pollution. Distinct from the two detached functional components (photothermal agent and photocatalyst) in a conventional evaporator, in this study, an all-in-one photothermal/catalytic agent, nitrogen-containing honeycomb carbon nanosheets (NHC), was engineered for synergistic high-efficiency steam generation and photocatalysis functions. It was demonstrated that the superoxide radical generated on the surface of NHC conferred its catalytic activity to the photodegradation of organic pollutants under full solar spectrum irradiation.
View Article and Find Full Text PDFMicroorganisms
January 2025
Laboratory of Microbial Enzymology, G.K. Skryabin Institute of Biochemistry and Physiology of Microorganisms, Pushchino Scientific Center for Biological Research, Russian Academy of Sciences, Prosp. Nauki 5, 142290 Pushchino, Russia.
Phenolic compounds are an extensive group of natural and anthropogenic organic substances of the aromatic series containing one or more hydroxyl groups. The main sources of phenols entering the environment are waste from metallurgy and coke plants, enterprises of the leather, furniture, and pulp and paper industries, as well as wastewater from the production of phenol-formaldehyde resins, adhesives, plastics, and pesticides. Among this group of compounds, phenol is the most common environmental pollutant.
View Article and Find Full Text PDFEnviron Sci Technol
January 2025
Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education, China), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, China.
Electrochemical oxidation via in situ-generated reactive oxygen species (ROS) is effective for the mineralization of refractory organic pollutants. However, the oxidation performance is usually limited by the low yield and utilization efficiency of ROS. Herein, a B/N-doped diamond (BND) flow-through electrode with enhanced SO/OH generation and utilization was designed for electrochemical oxidation of organic pollutants in sulfate solution.
View Article and Find Full Text PDFWater Res
January 2025
Yellow River Laboratory of Shanxi Province, Shanxi University, Taiyuan, 030006, PR China; The Key Laboratory of Water and Sediment Sciences (Ministry of Education), College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, PR China. Electronic address:
High-temperature wastewaters can themselves activate peroxydisulfate (PDS) to remove aromatic contaminants via polymerization. This, however, may result in an insufficient carbon source for denitrification during biochemical treatment, and the formed polymers, without a proper reuse method, will be costly to handle as hazardous waste. This study demonstrates that the addition of NaOH can suppress the polymerization of aromatic contaminants, which is observed not only in simulated wastewater but also in actual coking wastewater (ACW).
View Article and Find Full Text PDFWater Res
December 2024
Key Laboratory of the Three Gorges Reservoir Region's Eco-Environment, Ministry of Education, College of Environment and Ecology, Chongqing University, Chongqing 400045, China. Electronic address:
The peroxone reaction, a promising alternative technology for water treatment, is traditionally hampered by its restricted pH operational range and suboptimal oxidant utilization. In this study, we introduced a novel amphoteric metal oxide (ZnO)-regulated peroxone system that transcended the pH limitations of conventional peroxone processes. Our innovative approach exploited the unique properties of ZnO to regulate the reaction pathway of the traditional O/HO (or peroxymonosulfate, PMS) processes, resulting in a 52.
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